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- W2892848588 abstract "The reaction of the amidinatosilicon(I) dimer [LSi:]2 (1; L = PhC(NtBu)2) with FeBr2 in tetrahydrofuran (THF) at ambient temperature afforded the silicon(I)–iron(II) dimer [LSi(FeBr2·THF)]2 (2) after 40 h. Compound 2 can catalyze hydroboration of aliphatic and aromatic ketone compounds with HBpin in the absence of any strong reducing agent. Mechanistic studies show that complex 2 reacts with ketone compounds to form a zwitterionic intermediate in the first step of catalysis. Subsequent reaction with HBpin affords the corresponding boron esters and then regenerates complex 2." @default.
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- W2892848588 date "2018-09-24" @default.
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- W2892848588 title "Synthesis of a Base-Stabilized Silicon(I)–Iron(II) Complex for Hydroboration of Carbonyl Compounds" @default.
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- W2892848588 doi "https://doi.org/10.1021/acs.inorgchem.8b01760" @default.
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