FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2892871034> ?p ?o ?g. }

• W2892871034 abstract "The effect of deuteration on the thermal conductivity κ of water, crystalline ice, and amorphous ices was studied using the pressure induced amorphization of hexagonal ice, ice Ih, to obtain the deuterated, D2O, forms of low-density amorphous (LDA), high-density amorphous (HDA), and very-high density amorphous (VHDA) ices. Upon deuteration, κ of ice Ih decreases between 3% and 4% in the 100-270 K range at ambient pressure, but the effect diminishes on densification at 130 K and vanishes just prior to amorphization near 0.8 GPa. The unusual negative value of the isothermal density ρ dependence of κ for ice Ih, g = (d ln κ/d ln ρ)T = −4.4, is less so for deuterated ice: g = −3.8. In the case of the amorphous ices and liquid water, κ of water decreases by 3.5% upon deuteration at ambient conditions, whereas κ of HDA and VHDA ices instead increases by up to 5% for pressures up to 1.2 GPa at 130 K, despite HDA’s and VHDA’s structural similarities with water. The results are consistent with significant heat transport by librational modes in amorphous ices as well as water, and that deuteration increases phonon-phonon scattering in crystalline ice. Heat transport by librational modes is more pronounced in D2O than in H2O at low temperatures due to a deuteration-induced redshift of librational mode frequencies. Moreover, the results show that κ of deuterated LDA ice is 4% larger than that of normal LDA at 130 K, and both forms display an unusual temperature dependence of κ, which is reminiscent of that for crystals (κ ∼ T−1), and a unique negative pressure dependence of κ, which likely is linked to local-order structural similarities to ice Ih." @default.
• W2892871034 created "2018-10-05" @default.
• W2892871034 creator A5036841805 @default.
• W2892871034 date "2018-09-27" @default.
• W2892871034 modified "2023-09-24" @default.
• W2892871034 title "Thermal conductivity of normal and deuterated water, crystalline ice, and amorphous ices" @default.
• W2892871034 cites W1594855349 @default.
• W2892871034 cites W1966549165 @default.
• W2892871034 cites W1967090030 @default.
• W2892871034 cites W1973179204 @default.
• W2892871034 cites W1973772785 @default.
• W2892871034 cites W1974508138 @default.
• W2892871034 cites W1978877178 @default.
• W2892871034 cites W1980477791 @default.
• W2892871034 cites W1981295951 @default.
• W2892871034 cites W1986902574 @default.
• W2892871034 cites W1989948770 @default.
• W2892871034 cites W1990450668 @default.
• W2892871034 cites W1997962964 @default.
• W2892871034 cites W2002371371 @default.
• W2892871034 cites W2003921867 @default.
• W2892871034 cites W2004582014 @default.
• W2892871034 cites W2007031612 @default.
• W2892871034 cites W2010957208 @default.
• W2892871034 cites W2011074975 @default.
• W2892871034 cites W2011373764 @default.
• W2892871034 cites W2012008704 @default.
• W2892871034 cites W2020974426 @default.
• W2892871034 cites W2023170532 @default.
• W2892871034 cites W2027580422 @default.
• W2892871034 cites W2036115699 @default.
• W2892871034 cites W2043731326 @default.
• W2892871034 cites W2044590389 @default.
• W2892871034 cites W2046456886 @default.
• W2892871034 cites W2047435382 @default.
• W2892871034 cites W2055914612 @default.
• W2892871034 cites W2057249584 @default.
• W2892871034 cites W2062808943 @default.
• W2892871034 cites W2066782209 @default.
• W2892871034 cites W2067297550 @default.
• W2892871034 cites W2067900119 @default.
• W2892871034 cites W2071595714 @default.
• W2892871034 cites W2081483035 @default.
• W2892871034 cites W2081926166 @default.
• W2892871034 cites W2084260043 @default.
• W2892871034 cites W2085870168 @default.
• W2892871034 cites W2091087418 @default.
• W2892871034 cites W2098341769 @default.
• W2892871034 cites W2110873150 @default.
• W2892871034 cites W2131976200 @default.
• W2892871034 cites W2156058559 @default.
• W2892871034 cites W2159720252 @default.
• W2892871034 cites W2479414815 @default.
• W2892871034 cites W2490200188 @default.
• W2892871034 cites W2562301074 @default.
• W2892871034 cites W2563583614 @default.
• W2892871034 cites W2798087340 @default.
• W2892871034 cites W4255806036 @default.
• W2892871034 doi "https://doi.org/10.1063/1.5050172" @default.
• W2892871034 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30278676" @default.
• W2892871034 hasPublicationYear "2018" @default.
• W2892871034 type Work @default.
• W2892871034 sameAs 2892871034 @default.
• W2892871034 citedByCount "8" @default.
• W2892871034 countsByYear W28928710342020 @default.
• W2892871034 countsByYear W28928710342021 @default.
• W2892871034 countsByYear W28928710342022 @default.
• W2892871034 countsByYear W28928710342023 @default.
• W2892871034 crossrefType "journal-article" @default.
• W2892871034 hasAuthorship W2892871034A5036841805 @default.
• W2892871034 hasConcept C121332964 @default.
• W2892871034 hasConcept C126485055 @default.
• W2892871034 hasConcept C133347239 @default.
• W2892871034 hasConcept C159467904 @default.
• W2892871034 hasConcept C159985019 @default.
• W2892871034 hasConcept C178790620 @default.
• W2892871034 hasConcept C184779094 @default.
• W2892871034 hasConcept C185592680 @default.
• W2892871034 hasConcept C192562407 @default.
• W2892871034 hasConcept C2779529193 @default.
• W2892871034 hasConcept C2989277613 @default.
• W2892871034 hasConcept C32909587 @default.
• W2892871034 hasConcept C56052488 @default.
• W2892871034 hasConcept C58364064 @default.
• W2892871034 hasConcept C8010536 @default.
• W2892871034 hasConcept C97346530 @default.
• W2892871034 hasConcept C97355855 @default.
• W2892871034 hasConceptScore W2892871034C121332964 @default.
• W2892871034 hasConceptScore W2892871034C126485055 @default.
• W2892871034 hasConceptScore W2892871034C133347239 @default.
• W2892871034 hasConceptScore W2892871034C159467904 @default.
• W2892871034 hasConceptScore W2892871034C159985019 @default.
• W2892871034 hasConceptScore W2892871034C178790620 @default.
• W2892871034 hasConceptScore W2892871034C184779094 @default.
• W2892871034 hasConceptScore W2892871034C185592680 @default.
• W2892871034 hasConceptScore W2892871034C192562407 @default.
• W2892871034 hasConceptScore W2892871034C2779529193 @default.
• W2892871034 hasConceptScore W2892871034C2989277613 @default.
• W2892871034 hasConceptScore W2892871034C32909587 @default.
• W2892871034 hasConceptScore W2892871034C56052488 @default.

• next