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• W2892941296 endingPage "2027" @default.
• W2892941296 startingPage "2021" @default.
• W2892941296 abstract "Abstract We report a joint experimental and theoretical study of the lattice dynamics of cubic Tb 2 O 3 . Up to 16 optical Raman‐active modes have been observed with polarized and unpolarized Raman scattering measurements on a high‐quality Tb 2 O 3 single crystal. The measured wavenumbers have been compared with those of other rare‐earth (RE) and related sesquioxides with cubic (C‐type or bixbyite) structure. First‐principles calculations have allowed us to assign the symmetry of the experimentally observed Raman‐active modes. Additional lattice‐dynamical calculations on the related cubic RE sesquioxides Dy 2 O 3 , Gd 2 O 3 , Eu 2 O 3 , and Sm 2 O 3 indicate that the phonon wavenumbers of the Raman‐active modes in these compounds are monotonically reduced with increasing the lattice parameter along the Dy 2 O 3 ‐Tb 2 O 3 ‐Gd 2 O 3 ‐Eu 2 O 3 ‐Sm 2 O 3 series, thus prompting for a revision of the experimental Raman spectra of some of these compounds (mainly Eu 2 O 3 but also Gd 2 O 3 )." @default.
• W2892941296 created "2018-10-05" @default.
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• W2892941296 date "2018-09-25" @default.
• W2892941296 modified "2023-10-18" @default.
• W2892941296 title "Lattice dynamics study of cubic Tb ₂ O ₃" @default.
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• W2892941296 doi "https://doi.org/10.1002/jrs.5488" @default.
• W2892941296 hasPublicationYear "2018" @default.
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