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• W2892973902 abstract "The α-amidoalkylating properties of 1-(N-acylamino)alkyltriarylphosphonium salts with weakened Cα-P+ bond strength are discussed and examined. It is demonstrated that such type of phosphonium salts reacts smoothly with a diverse array of carbon- and heteroatom-based nucleophiles, including 1-morpholinocyclohexene, 1,3-dicarbonyl compounds, benzotriazole sodium salt, p-toluenesulfinate sodium salt, benzylamine, triarylphosphines, and other P-nucleophiles. Reactions are conducted at room temperature, in a short time (5–15 min) and mostly without catalysts. Simple work-up procedures result in good or very good yields of products. The structures of known compounds were established by spectroscopic methods and all new compounds have been fully characterized using 1H-, 13C-, 31P-NMR, IR spectroscopy, and high-resolution mass spectrometry. Mechanistic aspects of described transformations are also performed and discussed. It was demonstrated that unique properties make 1-(N-acylamino)alkyl-triarylphosphonium salts with weakened Cα-P+ bond strength interesting building blocks with great potential, especially in α-amidoalkylation reactions." @default.
• W2892973902 created "2018-10-05" @default.
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• W2892973902 date "2018-09-25" @default.
• W2892973902 modified "2023-10-05" @default.
• W2892973902 title "1-(N-Acylamino)alkyltriarylphosphonium Salts with Weakened Cα-P+ Bond Strength—Synthetic Applications" @default.
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• W2892973902 doi "https://doi.org/10.3390/molecules23102453" @default.
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