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- W2893012323 abstract "The title mol-ecule, C38H42N4O4, displays a helical structure induced by the combination of the C-C-C-C torsion angle [-10.8 (2)°] between two 2,3'-bipyridyl units attached to the 1,2-positions of the central benzene ring and consecutive connections between five aromatic rings through the meta- and ortho-positions. Intra-molecular C-H⋯π inter-actions between an H atom of a pyridine ring and the centroid of a another pyridine ring contributes to the stabilization of the helical structure. In the crystal, weak C-H⋯π inter-actions link the title mol-ecules into a two-dimensional supra-molecular network extending parallel to the ac plane, in which the mol-ecules with right- and left-handed helical structures are alternately arranged. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the mol-ecular packing is dominated by van der Waals inter-actions between neighbouring H atoms, as well as by C-H⋯π inter-actions. One isopropoxyl group is disordered over two sets of sites [occupancy ratio 0.715 (5):0.285 (5)]." @default.
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- W2893012323 date "2018-09-25" @default.
- W2893012323 modified "2023-10-17" @default.
- W2893012323 title "Crystal structure and Hirshfeld surface analysis of 1,2-bis(2′,6′-diisopropoxy-[2,3′-bipyridin]-6-yl)benzene" @default.
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- W2893012323 doi "https://doi.org/10.1107/s2056989018013002" @default.
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