Matches in SemOpenAlex for { <https://semopenalex.org/work/W2893048896> ?p ?o ?g. }
- W2893048896 endingPage "684" @default.
- W2893048896 startingPage "676" @default.
- W2893048896 abstract "Self-organized TiO2 nanotube arrays are characterized by gaps that separate the layers of oxide surrounding cylindrical pores. Nanotube layer growth is thought to involve oxide flow induced by mechanical stress associated with anodization. The mechanism of TiO2 nanotube initiation was studied with in situ stress measurements during anodization in ethylene glycol-water-fluoride solutions. Compressive stress changes due to initial growth of barrier oxide films were detected, along with significantly larger tensile and compressive stress changes that followed the appearance of gaps between nanotubes at the metal-oxide interface. Interrupted anodizing experiments revealed that the latter stress changes are due to chemical processes or open-circuit electrochemical reactions. Further evidence for such reactions was deduced from the calculation of apparent Ti valences below four from measurements of Ti metal consumption during anodization. The gaps between nanotubes are thought to result from local oxide delamination at the metal interface induced by oxide flow, and the large compressive stress change is attributed to chemical oxidation of Ti+3 ions in the nanotube walls. This previously unrecognized chemical oxidation reaction may suggests new avenues to control nanotube layer growth and properties." @default.
- W2893048896 created "2018-10-05" @default.
- W2893048896 creator A5027462161 @default.
- W2893048896 creator A5030041291 @default.
- W2893048896 creator A5039596368 @default.
- W2893048896 creator A5074192947 @default.
- W2893048896 date "2018-12-01" @default.
- W2893048896 modified "2023-09-23" @default.
- W2893048896 title "Roles of mechanical stress and lower-valent oxide in the formation of anodic titanium dioxide nanotube layers" @default.
- W2893048896 cites W1488595613 @default.
- W2893048896 cites W1966569996 @default.
- W2893048896 cites W1969474373 @default.
- W2893048896 cites W1969618807 @default.
- W2893048896 cites W1971303966 @default.
- W2893048896 cites W1971429527 @default.
- W2893048896 cites W1981003998 @default.
- W2893048896 cites W1986534042 @default.
- W2893048896 cites W1989100013 @default.
- W2893048896 cites W1989456217 @default.
- W2893048896 cites W1991273771 @default.
- W2893048896 cites W1991892582 @default.
- W2893048896 cites W2002056664 @default.
- W2893048896 cites W2007300833 @default.
- W2893048896 cites W2012585174 @default.
- W2893048896 cites W2014486832 @default.
- W2893048896 cites W2016590225 @default.
- W2893048896 cites W2016902821 @default.
- W2893048896 cites W2021646306 @default.
- W2893048896 cites W2031325460 @default.
- W2893048896 cites W2039151330 @default.
- W2893048896 cites W2041891329 @default.
- W2893048896 cites W2043289510 @default.
- W2893048896 cites W2055176540 @default.
- W2893048896 cites W2058914780 @default.
- W2893048896 cites W2060650362 @default.
- W2893048896 cites W2061468929 @default.
- W2893048896 cites W2067800515 @default.
- W2893048896 cites W2067926897 @default.
- W2893048896 cites W2071392928 @default.
- W2893048896 cites W2074765880 @default.
- W2893048896 cites W2075349371 @default.
- W2893048896 cites W2080158468 @default.
- W2893048896 cites W2082527859 @default.
- W2893048896 cites W2088667109 @default.
- W2893048896 cites W2089705030 @default.
- W2893048896 cites W2120033702 @default.
- W2893048896 cites W2159264562 @default.
- W2893048896 cites W2166601353 @default.
- W2893048896 cites W2328583773 @default.
- W2893048896 cites W2405845108 @default.
- W2893048896 cites W2411353123 @default.
- W2893048896 cites W2549837121 @default.
- W2893048896 cites W2727937639 @default.
- W2893048896 cites W2766793061 @default.
- W2893048896 cites W2793139993 @default.
- W2893048896 cites W3101719451 @default.
- W2893048896 doi "https://doi.org/10.1016/j.electacta.2018.09.182" @default.
- W2893048896 hasPublicationYear "2018" @default.
- W2893048896 type Work @default.
- W2893048896 sameAs 2893048896 @default.
- W2893048896 citedByCount "5" @default.
- W2893048896 countsByYear W28930488962019 @default.
- W2893048896 countsByYear W28930488962020 @default.
- W2893048896 countsByYear W28930488962021 @default.
- W2893048896 crossrefType "journal-article" @default.
- W2893048896 hasAuthorship W2893048896A5027462161 @default.
- W2893048896 hasAuthorship W2893048896A5030041291 @default.
- W2893048896 hasAuthorship W2893048896A5039596368 @default.
- W2893048896 hasAuthorship W2893048896A5074192947 @default.
- W2893048896 hasConcept C127413603 @default.
- W2893048896 hasConcept C138885662 @default.
- W2893048896 hasConcept C159985019 @default.
- W2893048896 hasConcept C166524527 @default.
- W2893048896 hasConcept C171250308 @default.
- W2893048896 hasConcept C191897082 @default.
- W2893048896 hasConcept C192562407 @default.
- W2893048896 hasConcept C21036866 @default.
- W2893048896 hasConcept C22016385 @default.
- W2893048896 hasConcept C2777593239 @default.
- W2893048896 hasConcept C2777619693 @default.
- W2893048896 hasConcept C2779851234 @default.
- W2893048896 hasConcept C41895202 @default.
- W2893048896 hasConcept C42360764 @default.
- W2893048896 hasConcept C506065880 @default.
- W2893048896 hasConcept C513153333 @default.
- W2893048896 hasConcept C513720949 @default.
- W2893048896 hasConceptScore W2893048896C127413603 @default.
- W2893048896 hasConceptScore W2893048896C138885662 @default.
- W2893048896 hasConceptScore W2893048896C159985019 @default.
- W2893048896 hasConceptScore W2893048896C166524527 @default.
- W2893048896 hasConceptScore W2893048896C171250308 @default.
- W2893048896 hasConceptScore W2893048896C191897082 @default.
- W2893048896 hasConceptScore W2893048896C192562407 @default.
- W2893048896 hasConceptScore W2893048896C21036866 @default.
- W2893048896 hasConceptScore W2893048896C22016385 @default.
- W2893048896 hasConceptScore W2893048896C2777593239 @default.
- W2893048896 hasConceptScore W2893048896C2777619693 @default.
- W2893048896 hasConceptScore W2893048896C2779851234 @default.