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• W2893049610 abstract "A scalable synthesis of chiral Vedejs-type DMAP catalysts is reported. The key step of the synthesis is amination of the enantiomerically pure 4-chloropyridine derivative using well-defined ZnCl2(amine)2 complexes. A series of Zn(II)–amine complexes have been synthesized to explore the scope of the ZnCl2-mediated amination of 4-halopyridines. Mechanistic studies support a Zn(II)-facilitated nucleophilic aromatic substitution as a plausible mechanism for the chlorine-to-amine exchange." @default.
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• W2893049610 date "2018-09-26" @default.
• W2893049610 modified "2023-10-17" @default.
• W2893049610 title "Preparative-Scale Synthesis of Vedejs Chiral DMAP Catalysts" @default.
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• W2893049610 doi "https://doi.org/10.1021/acs.joc.8b01687" @default.
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