FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2893148107> ?p ?o ?g. }

• W2893148107 endingPage "466" @default.
• W2893148107 startingPage "458" @default.
• W2893148107 abstract "Tetrachlorobenzenes represent one of the best known, but not yet fully understood, group of isomers of the structure–melting point relationship. The differences in melting temperatures of these structurally related compounds were rationalized in terms of the hierarchy and nature of formed noncovalent interactions, and the molecular aggregation that is influenced by molecular symmetry. The highest melting point is associated with the highly symmetric 1,2,4,5-tetrachlorobenzene isomer. The structures of less symmetrical 1,2,3,4-tetrachlorobenzene and 1,2,3,5-tetrachlorobenzene, determined at 270 and 90 K, show a distinct pattern of halogen bonds, characterized by the different numbers and types of interactions. The evolution of Cl...Cl/H distances with temperature indicates the attractive character of intermolecular interactions and their importance to the structural and thermodynamic parameters of isomeric compounds. The favoured Cl...Cl halogen bonds were found to play a decisive role in differentiating the melting temperatures of tetrachlorobenzene isomers. It was also found that, besides the molecular symmetry and ability to form specific intermolecular interactions, both the type and the distribution of interactions are the important factors responsible for the melting behaviour of the studied isomers. The observed preferences, in tetrachlorobenzenes, for the formation of specific noncovalent interactions correspond to the distribution of calculated partial atomic charges and to the magnitudes of electrostatic potential on the molecular surfaces as well as correlate with the enthalpy of melting parameters." @default.
• W2893148107 created "2018-10-05" @default.
• W2893148107 creator A5086563774 @default.
• W2893148107 date "2018-09-27" @default.
• W2893148107 modified "2023-09-26" @default.
• W2893148107 title "Melting point, molecular symmetry and aggregation of tetrachlorobenzene isomers: the role of halogen bonding" @default.
• W2893148107 cites W1548914255 @default.
• W2893148107 cites W1968339413 @default.
• W2893148107 cites W1969360633 @default.
• W2893148107 cites W1970958927 @default.
• W2893148107 cites W1971152942 @default.
• W2893148107 cites W1979368277 @default.
• W2893148107 cites W1979453404 @default.
• W2893148107 cites W1982293718 @default.
• W2893148107 cites W1985415307 @default.
• W2893148107 cites W1994833914 @default.
• W2893148107 cites W1995158051 @default.
• W2893148107 cites W1998211534 @default.
• W2893148107 cites W2000935874 @default.
• W2893148107 cites W2000998616 @default.
• W2893148107 cites W2004331496 @default.
• W2893148107 cites W2004922260 @default.
• W2893148107 cites W2012488984 @default.
• W2893148107 cites W2013247584 @default.
• W2893148107 cites W2020375551 @default.
• W2893148107 cites W2023271753 @default.
• W2893148107 cites W2030756373 @default.
• W2893148107 cites W2030841140 @default.
• W2893148107 cites W2031735488 @default.
• W2893148107 cites W2033433496 @default.
• W2893148107 cites W2034697199 @default.
• W2893148107 cites W2040569586 @default.
• W2893148107 cites W2045695838 @default.
• W2893148107 cites W2053559466 @default.
• W2893148107 cites W2053631370 @default.
• W2893148107 cites W2057872195 @default.
• W2893148107 cites W2069592832 @default.
• W2893148107 cites W2075281527 @default.
• W2893148107 cites W2077080470 @default.
• W2893148107 cites W2077263538 @default.
• W2893148107 cites W2077432382 @default.
• W2893148107 cites W2085068184 @default.
• W2893148107 cites W2086957099 @default.
• W2893148107 cites W2090387874 @default.
• W2893148107 cites W2101846026 @default.
• W2893148107 cites W2109285601 @default.
• W2893148107 cites W2127805602 @default.
• W2893148107 cites W2129043362 @default.
• W2893148107 cites W2131350133 @default.
• W2893148107 cites W2156706821 @default.
• W2893148107 cites W2156958510 @default.
• W2893148107 cites W2166545091 @default.
• W2893148107 cites W2167286323 @default.
• W2893148107 cites W2265596863 @default.
• W2893148107 cites W2403635530 @default.
• W2893148107 cites W2531882265 @default.
• W2893148107 cites W2587736282 @default.
• W2893148107 cites W2773725512 @default.
• W2893148107 cites W2780769889 @default.
• W2893148107 cites W4250130851 @default.
• W2893148107 cites W78337159 @default.
• W2893148107 doi "https://doi.org/10.1107/s2052520618012295" @default.
• W2893148107 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30297552" @default.
• W2893148107 hasPublicationYear "2018" @default.
• W2893148107 type Work @default.
• W2893148107 sameAs 2893148107 @default.
• W2893148107 citedByCount "5" @default.
• W2893148107 countsByYear W28931481072019 @default.
• W2893148107 countsByYear W28931481072020 @default.
• W2893148107 countsByYear W28931481072021 @default.
• W2893148107 countsByYear W28931481072023 @default.
• W2893148107 crossrefType "journal-article" @default.
• W2893148107 hasAuthorship W2893148107A5086563774 @default.
• W2893148107 hasConcept C112887158 @default.
• W2893148107 hasConcept C121332964 @default.
• W2893148107 hasConcept C13530604 @default.
• W2893148107 hasConcept C137277065 @default.
• W2893148107 hasConcept C147597530 @default.
• W2893148107 hasConcept C159467904 @default.
• W2893148107 hasConcept C166950319 @default.
• W2893148107 hasConcept C178790620 @default.
• W2893148107 hasConcept C185592680 @default.
• W2893148107 hasConcept C21582691 @default.
• W2893148107 hasConcept C23029723 @default.
• W2893148107 hasConcept C2780263894 @default.
• W2893148107 hasConcept C3288061 @default.
• W2893148107 hasConcept C32909587 @default.
• W2893148107 hasConcept C37197862 @default.
• W2893148107 hasConcept C46062151 @default.
• W2893148107 hasConcept C8010536 @default.
• W2893148107 hasConcept C97355855 @default.
• W2893148107 hasConceptScore W2893148107C112887158 @default.
• W2893148107 hasConceptScore W2893148107C121332964 @default.
• W2893148107 hasConceptScore W2893148107C13530604 @default.
• W2893148107 hasConceptScore W2893148107C137277065 @default.
• W2893148107 hasConceptScore W2893148107C147597530 @default.
• W2893148107 hasConceptScore W2893148107C159467904 @default.
• W2893148107 hasConceptScore W2893148107C166950319 @default.

• next