Matches in SemOpenAlex for { <https://semopenalex.org/work/W2893149841> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2893149841 endingPage "364" @default.
- W2893149841 startingPage "358" @default.
- W2893149841 abstract "Alkyl siloxy functionalization increases the solubility of polyhedral oligomeric silsesquioxanes (POSS) in supercritical carbon dioxide over an order of magnitude compared to its counterpart with fluoroalkyl groups. The studied component, octatrimethylsiloxy POSS also exhibits higher solubility than other previously studied POSS types with various alkyl and methacryl groups. The octatrimethylsiloxy POSS-CO2 solid-vapor equilibrium curves have been constructed at temperatures between 308 and 328 K by measuring cloud points. The highest measured solubility of octatrimethylsiloxy POSS was 0.176 wt. fr., corresponding to 0.0083 mol fr., at 13.36 MPa, 328 K, and CO2 density of 0.59 g/cm3. The solubility versus CO2 density isotherms fall on a master curve up to about 2 × 10−3 mol fraction, while at higher concentrations, higher solubility was attained with increasing temperature. The experimental data were correlated using various semi-empirical density-based models which provided satisfactory correlations." @default.
- W2893149841 created "2018-10-05" @default.
- W2893149841 creator A5002121637 @default.
- W2893149841 creator A5059735234 @default.
- W2893149841 date "2019-01-01" @default.
- W2893149841 modified "2023-09-27" @default.
- W2893149841 title "Enhanced solubility of siloxy-modified polyhedral oligomeric silsesquioxanes in supercritical carbon dioxide" @default.
- W2893149841 cites W1581414230 @default.
- W2893149841 cites W1631906105 @default.
- W2893149841 cites W1964029894 @default.
- W2893149841 cites W1969782280 @default.
- W2893149841 cites W1976851856 @default.
- W2893149841 cites W1977570121 @default.
- W2893149841 cites W1979145785 @default.
- W2893149841 cites W1980339632 @default.
- W2893149841 cites W1983404147 @default.
- W2893149841 cites W1985166080 @default.
- W2893149841 cites W1998952788 @default.
- W2893149841 cites W2001058220 @default.
- W2893149841 cites W2001548444 @default.
- W2893149841 cites W2008368662 @default.
- W2893149841 cites W2008790693 @default.
- W2893149841 cites W2013121806 @default.
- W2893149841 cites W2020811150 @default.
- W2893149841 cites W2027609334 @default.
- W2893149841 cites W2028424901 @default.
- W2893149841 cites W2030345112 @default.
- W2893149841 cites W2035185475 @default.
- W2893149841 cites W2062027369 @default.
- W2893149841 cites W2068728652 @default.
- W2893149841 cites W2072879586 @default.
- W2893149841 cites W2078244207 @default.
- W2893149841 cites W2083931422 @default.
- W2893149841 cites W2084539322 @default.
- W2893149841 cites W2135480978 @default.
- W2893149841 cites W2153089510 @default.
- W2893149841 cites W2167840082 @default.
- W2893149841 cites W2321629522 @default.
- W2893149841 cites W2327071348 @default.
- W2893149841 cites W2414968615 @default.
- W2893149841 cites W2467083765 @default.
- W2893149841 cites W2517788694 @default.
- W2893149841 cites W2611377272 @default.
- W2893149841 cites W2806783586 @default.
- W2893149841 cites W73273978 @default.
- W2893149841 doi "https://doi.org/10.1016/j.supflu.2018.09.015" @default.
- W2893149841 hasPublicationYear "2019" @default.
- W2893149841 type Work @default.
- W2893149841 sameAs 2893149841 @default.
- W2893149841 citedByCount "6" @default.
- W2893149841 countsByYear W28931498412019 @default.
- W2893149841 countsByYear W28931498412020 @default.
- W2893149841 countsByYear W28931498412021 @default.
- W2893149841 crossrefType "journal-article" @default.
- W2893149841 hasAuthorship W2893149841A5002121637 @default.
- W2893149841 hasAuthorship W2893149841A5059735234 @default.
- W2893149841 hasConcept C100293340 @default.
- W2893149841 hasConcept C118419359 @default.
- W2893149841 hasConcept C127413603 @default.
- W2893149841 hasConcept C134458231 @default.
- W2893149841 hasConcept C155574463 @default.
- W2893149841 hasConcept C178790620 @default.
- W2893149841 hasConcept C185592680 @default.
- W2893149841 hasConcept C188027245 @default.
- W2893149841 hasConcept C2780263894 @default.
- W2893149841 hasConcept C42360764 @default.
- W2893149841 hasConcept C530467964 @default.
- W2893149841 hasConceptScore W2893149841C100293340 @default.
- W2893149841 hasConceptScore W2893149841C118419359 @default.
- W2893149841 hasConceptScore W2893149841C127413603 @default.
- W2893149841 hasConceptScore W2893149841C134458231 @default.
- W2893149841 hasConceptScore W2893149841C155574463 @default.
- W2893149841 hasConceptScore W2893149841C178790620 @default.
- W2893149841 hasConceptScore W2893149841C185592680 @default.
- W2893149841 hasConceptScore W2893149841C188027245 @default.
- W2893149841 hasConceptScore W2893149841C2780263894 @default.
- W2893149841 hasConceptScore W2893149841C42360764 @default.
- W2893149841 hasConceptScore W2893149841C530467964 @default.
- W2893149841 hasLocation W28931498411 @default.
- W2893149841 hasOpenAccess W2893149841 @default.
- W2893149841 hasPrimaryLocation W28931498411 @default.
- W2893149841 hasRelatedWork W1963653379 @default.
- W2893149841 hasRelatedWork W2051956325 @default.
- W2893149841 hasRelatedWork W2081591825 @default.
- W2893149841 hasRelatedWork W2094774254 @default.
- W2893149841 hasRelatedWork W2123970230 @default.
- W2893149841 hasRelatedWork W2233688293 @default.
- W2893149841 hasRelatedWork W252441951 @default.
- W2893149841 hasRelatedWork W2609949856 @default.
- W2893149841 hasRelatedWork W2763312086 @default.
- W2893149841 hasRelatedWork W930150328 @default.
- W2893149841 hasVolume "143" @default.
- W2893149841 isParatext "false" @default.
- W2893149841 isRetracted "false" @default.
- W2893149841 magId "2893149841" @default.
- W2893149841 workType "article" @default.