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- W2893165958 abstract "Two Pr-doped ceria nanocrystals with different morphologies (nanocubes and nanorods) were synthesized and used as supports to evaluate the effect of the interface regulation by Pr ions on the structure-sensitive ammonia synthesis reaction activity. The Ru/r-Ce0.8Pr0.2O2 has a higher activity (2 297.1 μmol/(g·h)) than that of Ru/c-Ce0.8Pr0.2O2(887.6 μmol/(g·h)) under the reaction condition of 400℃ and 1 MPa. In addition, the promoter Cs can effectively enhance the catalytic activity of catalysts such as 2Cs-Ru/r-Ce0.8Pr0.2O2 (13 698.6 μmol/(g·h)) and 2Cs-Ru/c-Ce0.8Pr0.2O2(7 667.7 μmol/(g·h)). The effect of the plane of Ce0.8Pr0.2O2 support on the catalytic performance of Ru/Ce0.8Pr0.2O2 and 2Cs-Ru/Ce0.8Pr0.2O2 catalysts could be correlated to the Pr doping into CeO2 altered the interface properties (composition and electron structure) between the Ru nanoparticles and the Ce0.8Pr0.2O2 support." @default.
- W2893165958 created "2018-10-05" @default.
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- W2893165958 date "2018-06-25" @default.
- W2893165958 modified "2023-10-03" @default.
- W2893165958 title "Effect of Interface Regulation Between Ru and the Ce 0.8 Pr 0.2 O 2 Support on the Activity of Ammonia Synthesis" @default.
- W2893165958 hasPublicationYear "2018" @default.
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