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• W2893213227 endingPage "6692" @default.
• W2893213227 startingPage "6682" @default.
• W2893213227 abstract "Synthesis of novel five‐ and six‐membered heteroaromatic sulfonyl fluorides bearing bromine atom at various positions of the heterocyclic ring is described. The synthetic utility of these compounds is demonstrated by the Suzuki, Stille, and Negishi cross‐coupling reactions, which proceeded chemoselectively at the aryl bromide moiety with 69–98 % yields. The tolerance of the SO 2 F group towards the coupling reaction conditions was confirmed in most of the experiments. The proposed method was efficient for either sp 2 –sp 2 or sp 2 –sp 3 C–C couplings. The developed procedure provides rapid access to various substituted heterocyclic sulfonyl fluorides." @default.
• W2893213227 created "2018-10-05" @default.
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• W2893213227 date "2018-11-27" @default.
• W2893213227 modified "2023-10-17" @default.
• W2893213227 title "Hetaryl Bromides Bearing the SO₂F Group – Versatile Substrates for Palladium‐Catalyzed C–C Coupling Reactions" @default.
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• W2893213227 doi "https://doi.org/10.1002/ejoc.201801270" @default.
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