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• W2893225553 startingPage "1354" @default.
• W2893225553 abstract "The triplesalen complex [Mn III 6 Cr III ] (ClO 4 ) 3 was synthesized and characterized by single‐crystal X‐ray diffraction, UV/Vis/NIR spectroscopy, and DC and AC magnetic susceptibilities. The molecular structure is D 3 symmetric, whereas all other salts and solvates of [Mn III 6 Cr III ] 3+ are S 6 symmetric. The UV/Vis/NIR spectrum of D 3 symmetric [Mn III 6 Cr III ] 3+ is almost identical to that of S 6 symmetric [Mn III 6 Cr III ] 3+ demonstrating that the electronic structure is not significantly perturbed by the symmetry variation. The magnetic data of D 3 symmetric [Mn III 6 Cr III ] 3+ is also similar to those of S 6 symmetric [Mn III 6 Cr III ] 3+ with antiferromagnetic J Mn–Mn exchange coupling. This is in contrast to the ferromagnetic J Mn–Mn exchange coupling in the chiral RR [Mn III 6 Cr III ] 3+ synthesized with a chiral triplesalen derivative. Due to the chirality, RR [Mn III 6 Cr III ] 3+ is also of D 3 symmetry. However, its UV/Vis/NIR spectrum differs to those of D 3 and S 6 symmetric [Mn III 6 Cr III ] 3+ . This indicates that the electronic and magnetic properties of RR [Mn III 6 Cr III ] 3+ are not different to those of [Mn III 6 Cr III ] 3+ due to the symmetry variation but due to the specific properties of the two triplesalen ligands." @default.
• W2893225553 created "2018-10-05" @default.
• W2893225553 creator A5014503882 @default.
• W2893225553 creator A5034905005 @default.
• W2893225553 creator A5054801266 @default.
• W2893225553 creator A5067506502 @default.
• W2893225553 date "2018-09-23" @default.
• W2893225553 modified "2023-09-25" @default.
• W2893225553 title "Does Symmetry Influence the Properties of [MnIII6CrIII]3+Single-Molecule Magnets?" @default.
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• W2893225553 doi "https://doi.org/10.1002/zaac.201800309" @default.
• W2893225553 hasPublicationYear "2018" @default.
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