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- W2893275328 abstract "The electrical conductivity and its real and imaginary permittivity parameters were studied over two vanadium-containing catalysts for the selective oxidation of n-butane to maleic anhydride. Parameter variation under isothermal conditions allowed determination of multiple steady-state conditions for catalytic performance and charge carrier dynamics. One sample was the n-type semiconductor V2O5–x with low selectivity, and the other sample was the p-type semiconductor vanadyl pyrophosphate (VPP) with high selectivity for the target product. Well-resolved conductivity parameters supported by in situ UV–vis studies allowed correlations between performance and charge carrier dynamics. A concept for interpreting the trends is presented, and consequences for further analytical work as well as for material design are derived." @default.
- W2893275328 created "2018-10-05" @default.
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- W2893275328 date "2018-09-27" @default.
- W2893275328 modified "2023-09-24" @default.
- W2893275328 title "Operando Electrical Conductivity and Complex Permittivity Study on Vanadia Oxidation Catalysts" @default.
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- W2893275328 doi "https://doi.org/10.1021/acs.jpcc.8b07417" @default.
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