FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2893297271> ?p ?o ?g. }

• W2893297271 endingPage "747" @default.
• W2893297271 startingPage "743" @default.
• W2893297271 abstract "The reduction of CO2 into formic acid or its conjugate base, using dihydrogen, is an attractive process. While catalysts based on noble metals have shown high turnover numbers, the use of abundant first-row metals is underdeveloped. The key steps of the reaction are CO2 insertion into a metal hydride and regeneration of the metal hydride with H2, along with the concomitant production of formate. For the first step, copper is known as one of the most efficient metals, as shown by the numerous copper-catalysed carboxylation reactions, but this metal has difficulties activating H2 to achieve the second step. Here, we report a catalytic system involving a stable copper hydride that activates CO2, working in tandem with a Lewis pair that heterolytically splits H2. In this system, unprecedented turnover numbers for copper are obtained. Surprisingly, through a combination of stoichiometric and catalytic reactions, we show that classical Lewis pairs outperform frustrated Lewis pairs in this process. Due to its ready availability and low cost, copper is an attractive metal for the homogeneous reduction of CO2 to formate. However, although CO2 can readily insert into copper hydrides to produce metal-bound formate, subsequent regeneration of the catalytic species with H2 is more challenging. Here a dual strategy is used, whereby a copper hydride activates CO2 and a Lewis pair heterolytically splits H2, leading to dramatically improved performance." @default.
• W2893297271 created "2018-10-05" @default.
• W2893297271 creator A5007477127 @default.
• W2893297271 creator A5019278344 @default.
• W2893297271 creator A5027187253 @default.
• W2893297271 creator A5039772963 @default.
• W2893297271 creator A5053752116 @default.
• W2893297271 creator A5071900541 @default.
• W2893297271 creator A5072837052 @default.
• W2893297271 date "2018-10-01" @default.
• W2893297271 modified "2023-10-01" @default.
• W2893297271 title "Tandem copper hydride–Lewis pair catalysed reduction of carbon dioxide into formate with dihydrogen" @default.
• W2893297271 cites W1907157165 @default.
• W2893297271 cites W1975506590 @default.
• W2893297271 cites W1981600895 @default.
• W2893297271 cites W1994567008 @default.
• W2893297271 cites W2005370295 @default.
• W2893297271 cites W2032122980 @default.
• W2893297271 cites W2033067297 @default.
• W2893297271 cites W2033923150 @default.
• W2893297271 cites W2042926180 @default.
• W2893297271 cites W2069309241 @default.
• W2893297271 cites W2079418194 @default.
• W2893297271 cites W2094413778 @default.
• W2893297271 cites W2095651803 @default.
• W2893297271 cites W2122681459 @default.
• W2893297271 cites W2128703814 @default.
• W2893297271 cites W2136726885 @default.
• W2893297271 cites W2143453620 @default.
• W2893297271 cites W2151640189 @default.
• W2893297271 cites W2156583367 @default.
• W2893297271 cites W2163579970 @default.
• W2893297271 cites W2171515789 @default.
• W2893297271 cites W2180641709 @default.
• W2893297271 cites W2235446592 @default.
• W2893297271 cites W2285239204 @default.
• W2893297271 cites W2287468570 @default.
• W2893297271 cites W2296880544 @default.
• W2893297271 cites W2310317481 @default.
• W2893297271 cites W2312952953 @default.
• W2893297271 cites W2315296405 @default.
• W2893297271 cites W2329384318 @default.
• W2893297271 cites W2332056529 @default.
• W2893297271 cites W2414938886 @default.
• W2893297271 cites W2476839356 @default.
• W2893297271 cites W2490179736 @default.
• W2893297271 cites W2495203519 @default.
• W2893297271 cites W2550399556 @default.
• W2893297271 cites W2560096417 @default.
• W2893297271 cites W2594918493 @default.
• W2893297271 cites W2604156473 @default.
• W2893297271 cites W2610290040 @default.
• W2893297271 cites W2619342739 @default.
• W2893297271 cites W2725648806 @default.
• W2893297271 cites W2761959175 @default.
• W2893297271 cites W2790636298 @default.
• W2893297271 cites W2794979826 @default.
• W2893297271 cites W4243660581 @default.
• W2893297271 cites W652280517 @default.
• W2893297271 doi "https://doi.org/10.1038/s41929-018-0140-3" @default.
• W2893297271 hasPublicationYear "2018" @default.
• W2893297271 type Work @default.
• W2893297271 sameAs 2893297271 @default.
• W2893297271 citedByCount "80" @default.
• W2893297271 countsByYear W28932972712018 @default.
• W2893297271 countsByYear W28932972712019 @default.
• W2893297271 countsByYear W28932972712020 @default.
• W2893297271 countsByYear W28932972712021 @default.
• W2893297271 countsByYear W28932972712022 @default.
• W2893297271 countsByYear W28932972712023 @default.
• W2893297271 crossrefType "journal-article" @default.
• W2893297271 hasAuthorship W2893297271A5007477127 @default.
• W2893297271 hasAuthorship W2893297271A5019278344 @default.
• W2893297271 hasAuthorship W2893297271A5027187253 @default.
• W2893297271 hasAuthorship W2893297271A5039772963 @default.
• W2893297271 hasAuthorship W2893297271A5053752116 @default.
• W2893297271 hasAuthorship W2893297271A5071900541 @default.
• W2893297271 hasAuthorship W2893297271A5072837052 @default.
• W2893297271 hasBestOaLocation W28932972714 @default.
• W2893297271 hasConcept C111335779 @default.
• W2893297271 hasConcept C159985019 @default.
• W2893297271 hasConcept C161790260 @default.
• W2893297271 hasConcept C163638829 @default.
• W2893297271 hasConcept C178790620 @default.
• W2893297271 hasConcept C179104552 @default.
• W2893297271 hasConcept C185592680 @default.
• W2893297271 hasConcept C192562407 @default.
• W2893297271 hasConcept C24596552 @default.
• W2893297271 hasConcept C2524010 @default.
• W2893297271 hasConcept C2777814067 @default.
• W2893297271 hasConcept C2777961443 @default.
• W2893297271 hasConcept C2780178953 @default.
• W2893297271 hasConcept C33923547 @default.
• W2893297271 hasConcept C512735826 @default.
• W2893297271 hasConcept C512968161 @default.
• W2893297271 hasConcept C530467964 @default.
• W2893297271 hasConcept C544778455 @default.
• W2893297271 hasConceptScore W2893297271C111335779 @default.

• next