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• W2893316497 abstract "ABSTRACT Temperature‐responsive polymers have recently gained importance due to their applications in drug delivery. Herein, temperature‐responsive graft copolymer (Alg‐ g ‐PDEAAm) of alginate and N , N ‐diethylacrylamide was synthesized by microwave‐assisted copolymerization using potassium persulfate/ N , N , N ′, N ′‐tetramethylethylenediamine initiator system. The reaction conditions for the best grafting (331%) have been optimized by changing microwave irradiation time, temperature, N , N ‐diethylacrylamide, and alginate concentrations. The spectroscopic characteristic, thermal properties, and surface morphology of the copolymers were investigated by FTIR, 1 H‐NMR, DSC/TGA, XRD, gel permeation chromatography, and SEM. Furthermore, low critical solution temperatures of Alg‐ g ‐PDEAAm copolymers were detected by UV spectroscopy. Swelling ratio of graft microspheres was carried out at 25, 32, and 37 °C, and microspheres were found exhibiting temperature‐responsive property. Cytotoxicity test indicated the Alg‐ g ‐PDEAAm copolymer and its microsphere were biocompatible. Therefore, based on the results the synthesized temperature‐responsive copolymer could be considered as a promising biomaterial. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46688." @default.
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• W2893316497 date "2018-09-22" @default.
• W2893316497 modified "2023-10-14" @default.
• W2893316497 title "Temperature‐responsive alginate‐<i>g</i>‐poly(<i>N</i>,<i>N</i>‐diethylacrylamide) copolymer: Synthesis, characterization, and swelling behavior" @default.
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• W2893316497 doi "https://doi.org/10.1002/app.46688" @default.
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