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- W2893333243 abstract "Effect of the reorientation motion of molecules and separate molecular fragments occurring between the positions with unequal potential energy, on the NQR frequency and the time T 1 of the spin-lattice relaxation of chemically and crystallographically nonequivalent resonant nuclei directly participating in the reorientational motion are considered. In the temperature dependences of these parameters, the following characteristic features are observed: the reorientational fade out temperatures of the resonant signals for nonequivalent nuclei can vary significantly; exponential (reorientational) parts of dependencies log T 1 vs 1/ T of these nuclei are parallel; the spin-lattice relaxation times caused by the reorientation mechanism become substantially longer. We discuss a qualitative relation of these features with the potential energy difference between the orientation positions on the one hand and with the angle between the rotation axis and the direction of the electric field gradient for nonequivalent quadrupole nuclei on the other hand." @default.
- W2893333243 created "2018-10-05" @default.
- W2893333243 creator A5007117623 @default.
- W2893333243 date "2018-01-01" @default.
- W2893333243 modified "2023-09-25" @default.
- W2893333243 title "Nuclear quadrupole resonance in crystals with reorientational motion between unequal potential wells" @default.
- W2893333243 doi "https://doi.org/10.17072/1994-3598-2018-2-35-44" @default.
- W2893333243 hasPublicationYear "2018" @default.
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