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• W2893343553 abstract "Stability of silver sulfide nanoparticle (Ag2S-NP) in the environment has recently drawn considerable attention since it is associated with environmental risk. Although the overestimated stability of Ag2S-NP in aqueous solution has already been recognized, studies on transformation of Ag2S-NP in environmental water are still very scarce. Here we reported that Ag2S-NP could undergo dissolution by manganese(IV) oxide (MnO2), an important naturally occurring oxidant in the environment, even in environmental water, although the dissolved silver would probably be adsorbed onto the particles (>0.45 μm) in environmental water, mitigating the measurable levels of dissolved silver. The extent and rate of Ag2S-NP dissolution rose with the increasing concentration of MnO2. In addition, environmental factors including natural organic matter, inorganic salts and organic acids could accelerate the Ag2S-NP dissolution by MnO2, wherein an increase in dissolution extent was also observed. We further documented that Ag2S-NP dissolution by MnO2 was highly dependent on O2 and it was an oxidative dissolution, with the production of SO42−. Finally, dissolution of Ag2S-NP by MnO2 affected zebra fish (Danio rerio) embryo viability, showing significant reduction in embryo survival and hatching rates, compared to embryos exposed to Ag2S-NP, MnO2 or dissolved manganese alone. These findings would further shed light on the stability of Ag2S-NP in the natural environment - essential for comprehensive nano risk assessment." @default.
• W2893343553 created "2018-10-05" @default.
• W2893343553 creator A5034694275 @default.
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• W2893343553 date "2018-12-01" @default.
• W2893343553 modified "2023-10-15" @default.
• W2893343553 title "Re-evaluation of stability and toxicity of silver sulfide nanoparticle in environmental water: Oxidative dissolution by manganese oxide" @default.
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• W2893343553 doi "https://doi.org/10.1016/j.envpol.2018.09.103" @default.
• W2893343553 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30267921" @default.
• W2893343553 hasPublicationYear "2018" @default.
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