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- W2893402708 abstract "Abstract The loss of the dihydrogen ligand from trans-[Ru(H2)H(dppe)2]+ cations (dppe = PPh2CH2CH2PPh2) in the solid state was investigated using 31P CP/MAS NMR spectroscopy and single crystal X-ray diffraction. While facile dihydrogen loss was observed at room temperature from crystalline samples with the large counteranions BPh4− and B(ArF)4−, ArF = 3,5-C6H3(CF3)2, it only occurred upon heating from complexes with the smaller anions BF4− and PF6−, resulting in the loss of crystallinity. Single crystal X-ray diffraction studies of the new complexes [RuH(dppe)2]BPh4 and trans-[Ru(H2)H(dppe)2]BArF4 are reported. A comparison of the crystal structures of square pyramidal [RuH(dppe)2]BPh4 and octahedral [Ru(H2)H(dppe)2]BPh4 shows that only minor structural changes occur upon loss of H2 from the crystal." @default.
- W2893402708 created "2018-10-05" @default.
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- W2893402708 date "2018-12-01" @default.
- W2893402708 modified "2023-09-24" @default.
- W2893402708 title "The effect of the counteranion on the loss of hydrogen from cationic ruthenium dihydrogen complexes in the solid state" @default.
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- W2893402708 doi "https://doi.org/10.1016/j.poly.2018.09.056" @default.
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