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- W2893406237 endingPage "12583" @default.
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- W2893406237 abstract "A direct access to α-iodoeones from iodonium ion and propargylic tosylates or acetates is described. Bis(pyridine) iodonium tetrafluoroborate (IPy2BF4, Barluenga’s reagent) promotes the rearrangement of these propargylic alcohol derivatives in mild conditions. The transformation gives β-unsubstituted, β-monosubstituted, and β,β-disubstituted α-iodoenones in high yields. β-Substituted α-iodoenones are obtained with excellent (Z)-selectivity." @default.
- W2893406237 created "2018-10-05" @default.
- W2893406237 creator A5019082977 @default.
- W2893406237 creator A5029987461 @default.
- W2893406237 creator A5079317048 @default.
- W2893406237 date "2018-09-24" @default.
- W2893406237 modified "2023-10-01" @default.
- W2893406237 title "Direct Synthesis of α-Iodoenones by IPy<sub>2</sub>BF<sub>4</sub>-Promoted Rearrangement of Propargylic Esters" @default.
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- W2893406237 doi "https://doi.org/10.1021/acs.joc.8b01746" @default.
- W2893406237 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30247033" @default.
- W2893406237 hasPublicationYear "2018" @default.
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