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- W2893413643 abstract "Bisulfite and sulfite (HSO3-/SO32-) are not only widely used toxic chemicals but also active anions with important biological functions. Hence, the development of new detection methods for HSO3-/SO32- is important for environmental security and human health. In this paper, we report a symmetrical hemicyanine for the detection of HSO3-/SO32-, SHC, which is constructed with p-diphthalaldehyde with trimethylbenzoindolium via condensation. The red fluorescent probe can fast respond to HSO3-/SO32- (<30 s) to give cyan fluorescence, and its sensing process is twice nucleophilic additions, which were observed from fluorescence response, initial ratiometric change, and subsequent turn-on increment; especially in a low-concentration level, the ratiometric fluorescence measurement can eliminate environmental interference. This probe can achieve a quantitative detection of HSO3-/SO32- in a wide concentration range. Furthermore, the probe SHC is a mitochondria-specific probe for ratiometric fluorescent detection of HSO3-/SO32- in living cells." @default.
- W2893413643 created "2018-10-05" @default.
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- W2893413643 date "2018-09-25" @default.
- W2893413643 modified "2023-10-16" @default.
- W2893413643 title "Two-Step Sensing, Colorimetric and Ratiometric Fluorescent Probe for Rapid Detection of Bisulfite in Aqueous Solutions and in Living Cells" @default.
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- W2893413643 doi "https://doi.org/10.1021/acsomega.8b01917" @default.
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