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- W2893436730 abstract "The strong π-acidity of the twelve CO ligands of [Fe4(μ4-N)(CO)12]− reduces the reactivity of the interstitial nitrogen atom. In their Communication on page 13057 ff., J. S. Figueroa et al. show that replacing four of the CO ligands with electron-donating m-terphenyl isocyanides (turbine generators) activates the nucleophilicity of the nitride (light bulb) such that cluster expansion is achieved by reaction with electrophiles (moths). Just as the moths create unevenness at the edge of the image, the resultant electron-rich iron clusters successfully mimic structural deformations of metal surfaces. The strong π-acidity of the twelve CO ligands of [Fe4(μ4-N)(CO)12]− reduces the reactivity of the interstitial nitrogen atom. In their Communication on page 13057 ff., J. S. Figueroa et al. show that replacing four of the CO ligands with electron-donating m-terphenyl isocyanides (turbine generators) activates the nucleophilicity of the nitride (light bulb) such that cluster expansion is achieved by reaction with electrophiles (moths). Just as the moths create unevenness at the edge of the image, the resultant electron-rich iron clusters successfully mimic structural deformations of metal surfaces. Proton-Conducting POMs Bioinorganic Chemistry Chirality" @default.
- W2893436730 created "2018-10-05" @default.
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- W2893436730 date "2018-08-20" @default.
- W2893436730 modified "2023-09-27" @default.
- W2893436730 title "Cover Picture: Controlled Expansion of a Strong‐Field Iron Nitride Cluster: Multi‐Site Ligand Substitution as a Strategy for Activating Interstitial Nitride Nucleophilicity (Angew. Chem. Int. Ed. 40/2018)" @default.
- W2893436730 doi "https://doi.org/10.1002/anie.201808887" @default.
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