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• W2893447321 abstract "Gold(I) thiolate compounds (i.e. AuI-SR) are important precursors for the synthesis of atomically precise Aun(SR)m nanoclusters. However, the nature of the AuI-SR precursor remains elusive. Here, we report that the Au10(TBBT)10 complex is a universal precursor for the synthesis of Aun(TBBT)m nanoclusters (where TBBT=4-tertbutylbenzenethiol/thiolate). Interestingly, the Au10(TBBT)10 complex is also found to be re-generated through extended etching of the Aun(SR)m nanoclusters with excess of TBBT thiol and O2. The formation of well-defined Au10(TBBT)10 complex, instead of polymeric AuI-SR, is attributed to the bulkiness of the TBBT thiol. Through 1D and 2D NMR characterization, the structure of Au10(TBBT)10 is correlated with the previously reported X-ray structure, which contains two inter-penetrated Au5(TBBT)5 rings. The photophysical property of Au10(TBBT)10complex is further probed by femtosecond transient absorption spectroscopy. The accessibility of the precise Au10(TBBT)10 precursor improves the efficiency of the synthesis of the Aun(TBBT)m nanoclusters and is expected to further facilitate excellent control and understanding of the reaction mechanisms of nanocluster synthesis." @default.
• W2893447321 created "2018-10-05" @default.
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• W2893447321 date "2018-08-01" @default.
• W2893447321 modified "2023-09-27" @default.
• W2893447321 title "Au₁₀(TBBT)₁₀: The beginning and the end of Au_<i>n</i>(TBBT)_<i>m</i> nanoclusters" @default.
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• W2893447321 doi "https://doi.org/10.1063/1674-0068/31/cjcp1806141" @default.
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