Matches in SemOpenAlex for { <https://semopenalex.org/work/W2893483852> ?p ?o ?g. }
- W2893483852 endingPage "769" @default.
- W2893483852 startingPage "769" @default.
- W2893483852 abstract "Formation of PdIn intermetallic nanoparticles supported on α-Al2O3 was investigated by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and hydrogen temperature-programmed desorption (H2-TPD) methods. The metals were loaded as heterobimetallic Pd(μ-O2CMe)4In(O2CMe) complex to ensure intimate contact between Pd and In. Reduction in H2 at 200 °C resulted in Pd-rich PdIn alloy as evidenced by XRD and the disappearance of Pd hydride. A minor amount of Pd1In1 intermetallic phase appeared after reduction at 200 °C and its formation was accomplished at 400 °C. Neither monometallic Pd or in nor other intermetallic structures were found after reduction at 400–600 °C. Catalytic performance of Pd1In1/α-Al2O3 was studied in the selective liquid-phase diphenylacetylene (DPA) hydrogenation. It was found that the reaction rate of undesired alkene hydrogenation is strongly reduced on Pd1In1 nanoparticles enabling effective kinetic control of the hydrogenation, and the catalyst demonstrated excellent selectivity to alkene." @default.
- W2893483852 created "2018-10-05" @default.
- W2893483852 creator A5004444741 @default.
- W2893483852 creator A5023535646 @default.
- W2893483852 creator A5028340095 @default.
- W2893483852 creator A5037651727 @default.
- W2893483852 creator A5064257292 @default.
- W2893483852 creator A5075181090 @default.
- W2893483852 creator A5087103681 @default.
- W2893483852 creator A5089940298 @default.
- W2893483852 date "2018-09-28" @default.
- W2893483852 modified "2023-10-12" @default.
- W2893483852 title "Highly-Ordered PdIn Intermetallic Nanostructures Obtained from Heterobimetallic Acetate Complex: Formation and Catalytic Properties in Diphenylacetylene Hydrogenation" @default.
- W2893483852 cites W1098473094 @default.
- W2893483852 cites W1626898839 @default.
- W2893483852 cites W1841356001 @default.
- W2893483852 cites W1920699699 @default.
- W2893483852 cites W1972446770 @default.
- W2893483852 cites W1980502263 @default.
- W2893483852 cites W2003320425 @default.
- W2893483852 cites W2008486574 @default.
- W2893483852 cites W2008902768 @default.
- W2893483852 cites W2012352105 @default.
- W2893483852 cites W2015740343 @default.
- W2893483852 cites W2020481794 @default.
- W2893483852 cites W2030537149 @default.
- W2893483852 cites W2034275169 @default.
- W2893483852 cites W2034785181 @default.
- W2893483852 cites W2038503712 @default.
- W2893483852 cites W2064340241 @default.
- W2893483852 cites W2076638846 @default.
- W2893483852 cites W2080859635 @default.
- W2893483852 cites W2085735252 @default.
- W2893483852 cites W2086132288 @default.
- W2893483852 cites W2113933656 @default.
- W2893483852 cites W2124666689 @default.
- W2893483852 cites W2139890307 @default.
- W2893483852 cites W2143799195 @default.
- W2893483852 cites W2151204301 @default.
- W2893483852 cites W2153292598 @default.
- W2893483852 cites W2169533829 @default.
- W2893483852 cites W2170951456 @default.
- W2893483852 cites W2232828257 @default.
- W2893483852 cites W2274244842 @default.
- W2893483852 cites W2316848292 @default.
- W2893483852 cites W2412998680 @default.
- W2893483852 cites W2465285673 @default.
- W2893483852 cites W2507860822 @default.
- W2893483852 cites W2509885778 @default.
- W2893483852 cites W2531158769 @default.
- W2893483852 cites W2531822912 @default.
- W2893483852 cites W2550995744 @default.
- W2893483852 cites W2556342852 @default.
- W2893483852 cites W2558904714 @default.
- W2893483852 cites W2559530993 @default.
- W2893483852 cites W2560749463 @default.
- W2893483852 cites W2613910893 @default.
- W2893483852 cites W2625137365 @default.
- W2893483852 cites W2708880996 @default.
- W2893483852 cites W2738472760 @default.
- W2893483852 cites W2739930952 @default.
- W2893483852 cites W2740247299 @default.
- W2893483852 cites W2757258599 @default.
- W2893483852 cites W2759096291 @default.
- W2893483852 cites W2763536371 @default.
- W2893483852 cites W2769826061 @default.
- W2893483852 cites W2783883563 @default.
- W2893483852 cites W2789816747 @default.
- W2893483852 cites W2889167949 @default.
- W2893483852 doi "https://doi.org/10.3390/nano8100769" @default.
- W2893483852 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6215092" @default.
- W2893483852 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30274218" @default.
- W2893483852 hasPublicationYear "2018" @default.
- W2893483852 type Work @default.
- W2893483852 sameAs 2893483852 @default.
- W2893483852 citedByCount "20" @default.
- W2893483852 countsByYear W28934838522019 @default.
- W2893483852 countsByYear W28934838522020 @default.
- W2893483852 countsByYear W28934838522021 @default.
- W2893483852 countsByYear W28934838522022 @default.
- W2893483852 countsByYear W28934838522023 @default.
- W2893483852 crossrefType "journal-article" @default.
- W2893483852 hasAuthorship W2893483852A5004444741 @default.
- W2893483852 hasAuthorship W2893483852A5023535646 @default.
- W2893483852 hasAuthorship W2893483852A5028340095 @default.
- W2893483852 hasAuthorship W2893483852A5037651727 @default.
- W2893483852 hasAuthorship W2893483852A5064257292 @default.
- W2893483852 hasAuthorship W2893483852A5075181090 @default.
- W2893483852 hasAuthorship W2893483852A5087103681 @default.
- W2893483852 hasAuthorship W2893483852A5089940298 @default.
- W2893483852 hasBestOaLocation W28934838521 @default.
- W2893483852 hasConcept C118792377 @default.
- W2893483852 hasConcept C161790260 @default.
- W2893483852 hasConcept C178790620 @default.
- W2893483852 hasConcept C179104552 @default.
- W2893483852 hasConcept C185592680 @default.
- W2893483852 hasConcept C191897082 @default.
- W2893483852 hasConcept C192562407 @default.