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- W2893515078 abstract "Effect of direct fluorination on interface discharge between isotactic polypropylene (PP) and silicone rubber (SiR) under AC voltage has been investigated. The influence of fluorination time on discharge initiation and propagation stages has been estimated. Water contact angle and surface roughness were measured to assist the understanding of fluorination effect on surface chemical and physical structures of sample. Obtained results showed that with the increase of fluorination time from 0 min to 15 min, the average surface roughness of PP increased from $sim 42~mathrm{nm}$ to $sim 65~mathrm{nm}$, whereas the water contact angle decreased from $sim 88^{circ}$ to $sim 58^{circ}$. In addition, the discharge initiation time increased from $sim 2~mathrm{s}$ to $sim 4~mathrm{s}$ but the discharge propagation time decreased from $sim 14~mathrm{s}$ to $sim 2~mathrm{s}$, leading to the reduction in overall time of interface breakdown from $sim 16~mathrm{s}$ to $sim 6~mathrm{s}$. It is suggested that at the initiation stage the C-F bond introduced by direct fluorination with higher bond energy and deeper trap depth should be responsible for the alleviation of polymer degradation, while at the propagation stage the formation of larger void at the surface tends to accelerate the degradation of polymer." @default.
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- W2893515078 date "2018-07-01" @default.
- W2893515078 modified "2023-09-22" @default.
- W2893515078 title "Effect of Surface Fluorination on Interface Discharge Behavior between Polypropylene and Silicone Rubber under AC Voltage" @default.
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- W2893515078 doi "https://doi.org/10.1109/icd.2018.8468396" @default.
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