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- W2893552667 abstract "Abstract The solubility of U(VI) is investigated from undersaturation conditions in 0.1, 0.51, 1.03, 3.31 and 4.58 m KCl–KOH solutions at pHm = 7.5–14.6 (with pHm = –log [H+] in molal units). All experiments were performed under Ar atmosphere at T = (22 ± 2)°C. XRD, quantitative chemical analysis, SEM–EDS and TG–DTA confirm that K2U2O7·1.5H2O(cr) is the solid phase controlling the solubility in all evaluated systems at pHm ≥ 9.5. Below this pHm and with decreasing KCl concentration, the formation of sub-stoichiometric phases with K:U" @default.
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- W2893552667 date "2018-11-01" @default.
- W2893552667 modified "2023-09-27" @default.
- W2893552667 title "Solubility of U(VI) in chloride solutions. II. The stable oxides/hydroxides in alkaline KCl solutions: Thermodynamic description and relevance in cementitious systems" @default.
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- W2893552667 doi "https://doi.org/10.1016/j.apgeochem.2018.09.017" @default.
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