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- W2893563118 abstract "Plant essential oils and their constituent monoterpenoids and phenylpropanoids have long been used as insect repellents. However, due to the low molecular weight of these compounds, vaporization is often rapid, leaving little residual repellent activity. Although sesquiterpenoids, as heavier, less volatile molecules, often have good repellent properties, these compounds are often less economically viable as repellents due to high production and isolation costs. With the objective of producing long-lasting repellents from cheaper starting materials, monoterpenoid and phenylpropanoid alcohols/phenols were esterified with isovaleric acid to produce a set of esters with molecular weights similar to sesquiterpenoids. A static-air repellency chamber was used to assay the repellency of the synthesized compounds against Culex pipiens. Most compounds showed significant repellency over the 150-minute duration of the short-term assay. Several compounds, particularly those derived from monocyclic monoterpenoids, retained substantial repellent effects in a long-term assay, indicating the potential for increased-duration insect repellents. Trends in the short-term assay are partially explained using solutions to the diffusion equation." @default.
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- W2893563118 date "2018-01-01" @default.
- W2893563118 modified "2023-10-16" @default.
- W2893563118 title "Monoterpenoid Isovalerate Esters as Long-Lasting Spatial Mosquito Repellents" @default.
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- W2893563118 doi "https://doi.org/10.1021/bk-2018-1289.ch011" @default.
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