Matches in SemOpenAlex for { <https://semopenalex.org/work/W2893611963> ?p ?o ?g. }
- W2893611963 endingPage "11981" @default.
- W2893611963 startingPage "11972" @default.
- W2893611963 abstract "Study of manganese oxides for electrocatalytic and photocatalytic oxidation of water is an active area of research. The starting material in this study is a high-surface-area disordered birnessite-like material with K+ in the interlayers (KMnOx). Upon ion-exchange with Fe3+, the disordered layer structure collapses (Fe(IE)MnOx), and the surface area is slightly increased. Structural analysis of the Fe(IE)MnOx included examination of its morphology, crystal structure, vibrational spectra, and manganese oxidation states. Using the Ru(bpy)32+-persulfate system, the dissolved and headspace oxygen upon visible light photolysis with highly dispersed Fe(IE)MnOx was measured. The photocatalytic activity for O2 evolution of the Fe(IE)MnOx was three times better than KMnOx, with the highest rate being 9.3 mmolO2 molMn-1 s-1. The improvement of the photocatalytic activity was proposed to arise from the increased disorder and interaction of Fe3+ with the MnO6 octahedra. As a benchmark, colloidal IrO2 was a better photocatalyst by a factor of ∼75 over Fe(IE)MnOx." @default.
- W2893611963 created "2018-10-05" @default.
- W2893611963 creator A5050225415 @default.
- W2893611963 creator A5052428546 @default.
- W2893611963 date "2018-09-26" @default.
- W2893611963 modified "2023-10-16" @default.
- W2893611963 title "Photochemical Water Oxidation in a Buffered Tris(2,2′-bipyridyl)ruthenium–Persulfate System Using Iron(III)-Modified Potassium Manganese Oxides as Catalysts" @default.
- W2893611963 cites W1964083672 @default.
- W2893611963 cites W1971975878 @default.
- W2893611963 cites W1975541332 @default.
- W2893611963 cites W1977211012 @default.
- W2893611963 cites W1983411294 @default.
- W2893611963 cites W1984278079 @default.
- W2893611963 cites W1986829915 @default.
- W2893611963 cites W1996839774 @default.
- W2893611963 cites W1997989685 @default.
- W2893611963 cites W2002292317 @default.
- W2893611963 cites W2008970158 @default.
- W2893611963 cites W2013741749 @default.
- W2893611963 cites W2020949743 @default.
- W2893611963 cites W2021076295 @default.
- W2893611963 cites W2025415294 @default.
- W2893611963 cites W2033033156 @default.
- W2893611963 cites W2037446136 @default.
- W2893611963 cites W2046328955 @default.
- W2893611963 cites W2058023944 @default.
- W2893611963 cites W2063145122 @default.
- W2893611963 cites W2066680777 @default.
- W2893611963 cites W2067384646 @default.
- W2893611963 cites W2079687321 @default.
- W2893611963 cites W2089866653 @default.
- W2893611963 cites W2098547240 @default.
- W2893611963 cites W2124007521 @default.
- W2893611963 cites W2126974786 @default.
- W2893611963 cites W2128701147 @default.
- W2893611963 cites W2128723739 @default.
- W2893611963 cites W2135785867 @default.
- W2893611963 cites W2142810237 @default.
- W2893611963 cites W2144730188 @default.
- W2893611963 cites W2153070782 @default.
- W2893611963 cites W2162961939 @default.
- W2893611963 cites W2171093931 @default.
- W2893611963 cites W2181161657 @default.
- W2893611963 cites W2204612655 @default.
- W2893611963 cites W2239259962 @default.
- W2893611963 cites W2289960406 @default.
- W2893611963 cites W2322029598 @default.
- W2893611963 cites W2324562428 @default.
- W2893611963 cites W2331608689 @default.
- W2893611963 cites W2341661453 @default.
- W2893611963 cites W2345643734 @default.
- W2893611963 cites W2408043908 @default.
- W2893611963 cites W2412436637 @default.
- W2893611963 cites W2418180711 @default.
- W2893611963 cites W2421795923 @default.
- W2893611963 cites W2525835939 @default.
- W2893611963 cites W2528535900 @default.
- W2893611963 cites W2530637881 @default.
- W2893611963 cites W2531056906 @default.
- W2893611963 cites W2556634034 @default.
- W2893611963 cites W2575733432 @default.
- W2893611963 cites W2605332128 @default.
- W2893611963 cites W2625624298 @default.
- W2893611963 cites W2733805983 @default.
- W2893611963 cites W2746387513 @default.
- W2893611963 cites W2801440538 @default.
- W2893611963 cites W630257549 @default.
- W2893611963 doi "https://doi.org/10.1021/acsomega.8b01918" @default.
- W2893611963 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6645209" @default.
- W2893611963 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31459281" @default.
- W2893611963 hasPublicationYear "2018" @default.
- W2893611963 type Work @default.
- W2893611963 sameAs 2893611963 @default.
- W2893611963 citedByCount "4" @default.
- W2893611963 countsByYear W28936119632021 @default.
- W2893611963 countsByYear W28936119632022 @default.
- W2893611963 crossrefType "journal-article" @default.
- W2893611963 hasAuthorship W2893611963A5050225415 @default.
- W2893611963 hasAuthorship W2893611963A5052428546 @default.
- W2893611963 hasBestOaLocation W28936119631 @default.
- W2893611963 hasConcept C161790260 @default.
- W2893611963 hasConcept C178790620 @default.
- W2893611963 hasConcept C179104552 @default.
- W2893611963 hasConcept C185592680 @default.
- W2893611963 hasConcept C192562407 @default.
- W2893611963 hasConcept C2775835284 @default.
- W2893611963 hasConcept C2778077586 @default.
- W2893611963 hasConcept C2778729139 @default.
- W2893611963 hasConcept C2779471666 @default.
- W2893611963 hasConcept C2781127917 @default.
- W2893611963 hasConcept C2993225395 @default.
- W2893611963 hasConcept C44228677 @default.
- W2893611963 hasConcept C521977710 @default.
- W2893611963 hasConcept C528890316 @default.
- W2893611963 hasConcept C55493867 @default.
- W2893611963 hasConcept C555196967 @default.
- W2893611963 hasConcept C65165184 @default.
- W2893611963 hasConcept C75473681 @default.