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• W2893627729 abstract "A new nonlinear optical crystals fluoride carbonate, Na4Yb(CO3)3F, has been synthesized by mild hydrothermal method. The Na4Yb(CO3)3F crystallizes in the noncentrosymmetric space group Cc (no. 9) with the lattice parameters a = 8.018(3), b = 15.929(5), c = 13.950(5) Å and β = 101.425(6)°. The compound Na4Yb(CO3)3F has a high density of [CO3] groups. The structure can be described as one-dimensional [Na5Yb(CO3)2F2] chains connected by [CO3] groups, forming an intricate three-dimensional (3D) framework. Other Na+ and Yb3+ cations are located in the cavities of 3D network. The powder second harmonic generation (SHG) measurement shows that Na4Yb(CO3)3F features a large SHG response, about 4.3 times that of KH2PO4 (KDP), and is a phase-matchable material. In addition, its UV-Vis-NIR diffuse reflectance spectral data indicate that Na4Yb(CO3)3F has a large optical gap about 4.72 eV, which corresponds to the UV cut-off edge of 263 nm." @default.
• W2893627729 created "2018-10-05" @default.
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• W2893627729 date "2018-09-30" @default.
• W2893627729 modified "2023-10-16" @default.
• W2893627729 title "Na4Yb(CO3)3F: A New UV Nonlinear Optical Material with a Large Second Harmonic Generation Response" @default.
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• W2893627729 doi "https://doi.org/10.3390/cryst8100381" @default.
• W2893627729 hasPublicationYear "2018" @default.
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