Matches in SemOpenAlex for { <https://semopenalex.org/work/W2893637150> ?p ?o ?g. }
- W2893637150 endingPage "169" @default.
- W2893637150 startingPage "163" @default.
- W2893637150 abstract "Two Cu(II) complexes, namely, [CuL12(OAc)2]·MeOH 1 and [CuL22(OAc)2] 2 (OAc = CH3COO, acetate), were synthesized based on two 1,2,4-triazole fungicides of paclobutrazol (L1) and diniconazole (L2). The crystal structural analysis shows that the two obtained complexes have similar structures and both of them adopt octahedral coordination mode. The Cu(II) atoms in both the complexes lie on a crystallographic inversion center and are coordinated with two triazole groups and two acetate anions. To screen effective fungicides, the two complexes were investigated for antifungal activities against four selected fungi using mycelial growth rate method. The results demonstrate that the toxicity of complex 2 was 6.96–23.39 times greater than that of complex 1, since complex 2 possesses both CC linkage and 2,4-dichlorobenzene moiety, and shows higher synergy levels for the molecular-level mixture of copper cation and L2. The results also show that both the synthesized complexes showed superior activities of 1.20–5.94 times to those of their ligands. The DFT calculation results of the title complexes and their ligands reveal that the complexes have a new active site of metal cation, smaller HOMO–LUMO energy gaps and lower polarity than their ligands, which should be responsible for the enhanced bioactivities after complexation." @default.
- W2893637150 created "2018-10-05" @default.
- W2893637150 creator A5004911199 @default.
- W2893637150 creator A5041275199 @default.
- W2893637150 creator A5080577523 @default.
- W2893637150 creator A5082091702 @default.
- W2893637150 creator A5089361676 @default.
- W2893637150 date "2019-01-01" @default.
- W2893637150 modified "2023-10-10" @default.
- W2893637150 title "Two Cu(II) complexes of 1,2,4-triazole fungicides with enhanced antifungal activities" @default.
- W2893637150 cites W1964433076 @default.
- W2893637150 cites W1968279994 @default.
- W2893637150 cites W1975654251 @default.
- W2893637150 cites W1977547367 @default.
- W2893637150 cites W1981368803 @default.
- W2893637150 cites W1981370222 @default.
- W2893637150 cites W1985166738 @default.
- W2893637150 cites W1999631834 @default.
- W2893637150 cites W2004407532 @default.
- W2893637150 cites W2007902417 @default.
- W2893637150 cites W2008322570 @default.
- W2893637150 cites W2010234679 @default.
- W2893637150 cites W2011534078 @default.
- W2893637150 cites W2012455645 @default.
- W2893637150 cites W2012862340 @default.
- W2893637150 cites W2019543107 @default.
- W2893637150 cites W2028753593 @default.
- W2893637150 cites W2028813195 @default.
- W2893637150 cites W2038990788 @default.
- W2893637150 cites W2044089306 @default.
- W2893637150 cites W2044549448 @default.
- W2893637150 cites W2069487236 @default.
- W2893637150 cites W2071719168 @default.
- W2893637150 cites W2077796804 @default.
- W2893637150 cites W2088465678 @default.
- W2893637150 cites W2092244272 @default.
- W2893637150 cites W2104901763 @default.
- W2893637150 cites W2131350133 @default.
- W2893637150 cites W2131842137 @default.
- W2893637150 cites W2140033415 @default.
- W2893637150 cites W2180760406 @default.
- W2893637150 cites W2208623846 @default.
- W2893637150 cites W2224781236 @default.
- W2893637150 cites W2285272855 @default.
- W2893637150 cites W2333776037 @default.
- W2893637150 cites W2734225105 @default.
- W2893637150 cites W2783341003 @default.
- W2893637150 cites W83972005 @default.
- W2893637150 doi "https://doi.org/10.1016/j.poly.2018.09.052" @default.
- W2893637150 hasPublicationYear "2019" @default.
- W2893637150 type Work @default.
- W2893637150 sameAs 2893637150 @default.
- W2893637150 citedByCount "11" @default.
- W2893637150 countsByYear W28936371502019 @default.
- W2893637150 countsByYear W28936371502020 @default.
- W2893637150 countsByYear W28936371502021 @default.
- W2893637150 countsByYear W28936371502022 @default.
- W2893637150 countsByYear W28936371502023 @default.
- W2893637150 crossrefType "journal-article" @default.
- W2893637150 hasAuthorship W2893637150A5004911199 @default.
- W2893637150 hasAuthorship W2893637150A5041275199 @default.
- W2893637150 hasAuthorship W2893637150A5080577523 @default.
- W2893637150 hasAuthorship W2893637150A5082091702 @default.
- W2893637150 hasAuthorship W2893637150A5089361676 @default.
- W2893637150 hasConcept C115624301 @default.
- W2893637150 hasConcept C155647269 @default.
- W2893637150 hasConcept C16005928 @default.
- W2893637150 hasConcept C178790620 @default.
- W2893637150 hasConcept C185592680 @default.
- W2893637150 hasConcept C198819137 @default.
- W2893637150 hasConcept C2776568683 @default.
- W2893637150 hasConcept C2777907353 @default.
- W2893637150 hasConcept C2779548794 @default.
- W2893637150 hasConcept C2780020378 @default.
- W2893637150 hasConcept C544153396 @default.
- W2893637150 hasConcept C544778455 @default.
- W2893637150 hasConcept C59822182 @default.
- W2893637150 hasConcept C71240020 @default.
- W2893637150 hasConcept C71924100 @default.
- W2893637150 hasConcept C74600772 @default.
- W2893637150 hasConcept C8010536 @default.
- W2893637150 hasConcept C86803240 @default.
- W2893637150 hasConceptScore W2893637150C115624301 @default.
- W2893637150 hasConceptScore W2893637150C155647269 @default.
- W2893637150 hasConceptScore W2893637150C16005928 @default.
- W2893637150 hasConceptScore W2893637150C178790620 @default.
- W2893637150 hasConceptScore W2893637150C185592680 @default.
- W2893637150 hasConceptScore W2893637150C198819137 @default.
- W2893637150 hasConceptScore W2893637150C2776568683 @default.
- W2893637150 hasConceptScore W2893637150C2777907353 @default.
- W2893637150 hasConceptScore W2893637150C2779548794 @default.
- W2893637150 hasConceptScore W2893637150C2780020378 @default.
- W2893637150 hasConceptScore W2893637150C544153396 @default.
- W2893637150 hasConceptScore W2893637150C544778455 @default.
- W2893637150 hasConceptScore W2893637150C59822182 @default.
- W2893637150 hasConceptScore W2893637150C71240020 @default.
- W2893637150 hasConceptScore W2893637150C71924100 @default.
- W2893637150 hasConceptScore W2893637150C74600772 @default.