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- W2893693977 abstract "The in-situ-generated zwitterionic allylic ylides between Morita–Baylis–Hillman carbonates from isatins and chiral tertiary amine catalysts underwent highly regioselective and enantioselective 1,3-oxo-ethynylation or 1,3-amino-sulfenylation reactions with silyl ethynyl-1,2-benziodoxol-3(1H)-ones or N-(aryl or alkylthio)imides, respectively, giving densely functionalized products bearing a quaternary stereogenic center. An array of diversely structured scaffolds were efficiently constructed from the products, showing the synthetic versatility of the current catalytic strategy." @default.
- W2893693977 created "2018-10-05" @default.
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- W2893693977 date "2018-09-26" @default.
- W2893693977 modified "2023-10-03" @default.
- W2893693977 title "Organocatalytic Enantioselective 1,3-Difunctionalizations of Morita–Baylis–Hillman Carbonates" @default.
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- W2893693977 doi "https://doi.org/10.1021/acs.orglett.8b02764" @default.
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