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- W2893724804 abstract "Abstract The direct enantioselective addition of water to unactivated alkenes could simplify the synthesis of chiral alcohols and solve a long‐standing challenge in catalysis. Here we report that an engineered fatty acid hydratase can catalyze the asymmetric hydration of various terminal and internal alkenes. In the presence of a carboxylic acid decoy molecule for activation of the oleate hydratase from E. meningoseptica , asymmetric hydration of unactivated alkenes was achieved with up to 93 % conversion, excellent selectivity (>99 % ee , >95 % regioselectivity), and on a preparative scale." @default.
- W2893724804 created "2018-10-05" @default.
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- W2893724804 date "2018-11-30" @default.
- W2893724804 modified "2023-10-09" @default.
- W2893724804 title "Asymmetric Enzymatic Hydration of Unactivated, Aliphatic Alkenes" @default.
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- W2893724804 doi "https://doi.org/10.1002/anie.201810005" @default.
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