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- W2893750901 abstract "A method for the synthesis of β‐trifluoromethyl ketones promoted by a base is described. In the presence of DBU, 1‐aryl‐4,4,4‐trifluoromethylbutanones with various functional groups were obtained through the reaction of 4‐aryl‐1,1,1‐trifluorobut‐2‐en‐2‐yl trifluoromethanesulfonates with water in moderate to excellent yields. The reaction underwent a double‐bond‐migration/hydrolysis/isomerization pathway, and 1‐aryl‐4,4,4‐trifluorobut‐2‐en‐1‐ols were determined as the key intermediates. Both electron‐withdrawing and electron‐donating groups, such as fluoro, chloro, bromo, ester, cyano, trifluoromethyl, alkyl, and alkoxy, were tolerated well in this reaction." @default.
- W2893750901 created "2018-10-05" @default.
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- W2893750901 date "2018-11-14" @default.
- W2893750901 modified "2023-09-23" @default.
- W2893750901 title "Base-Promoted Double-Bond-Migration/Hydrolysis/Isomerization of 4-Aryl-1,1,1-trifluorobut-2-en-2-yl Trifluoromethanesulfonates: A Metal-Free Approach to β-Trifluoromethyl Ketones" @default.
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- W2893750901 doi "https://doi.org/10.1002/ejoc.201801025" @default.
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