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- W2893757068 abstract "Abstract β‐(2‐Alkynylphenyl)‐α,β‐ynones undergo a gold‐catalyzed oxidative two‐fold cyclization in the presence of N ‐oxides to give 1,3‐disubstituted‐ 8H ‐indeno[1,2‐c]furan‐8‐ones in good yields. This cascade process is triggered by a selective oxygen transfer from an N ‐oxide onto the gold‐activated alkynone to generate a α‐dioxocarbene intermediate which, via carbene transfer across the remaining alkyne moiety and subsequent cyclization through nucleophilic attack by a carbonyl oxygen, achieves the construction of 1,3‐disubstituted fused polycyclic furans. magnified image" @default.
- W2893757068 created "2018-10-05" @default.
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- W2893757068 date "2018-11-14" @default.
- W2893757068 modified "2023-10-13" @default.
- W2893757068 title "Sequential Gold-Catalyzed Carbene Transfer/Ring Closure: Oxidative Cyclization of β-(2-Alkynylphenyl)-α,β-ynones to Indenofuranones" @default.
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- W2893757068 doi "https://doi.org/10.1002/adsc.201801082" @default.
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