Matches in SemOpenAlex for { <https://semopenalex.org/work/W2893803071> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2893803071 endingPage "3247" @default.
- W2893803071 startingPage "3243" @default.
- W2893803071 abstract "Reductive eliminations to form alkyl–nitrogen bonds are rare, and examples of this reaction from isolated complexes containing simple, unstabilized primary alkyl groups have not been observed. We report the synthesis of stable neopentylpalladium(II) anilido and methyleneamido complexes that undergo reductive elimination to form the C(sp3)–N bonds in N-neopentyl anilines and N-neopentyl imines, respectively. The synthesis and isolation of these complexes were enabled by weak chelation of palladium by P,O ancillary ligands. DFT calculations suggest that neopentylpalladium(II) complexes undergo reductive elimination by a concerted mechanism resembling a migration of the alkyl ligand to the nitrogen either following initial dissociation of the oxygen donor or in concert with lengthening of the Pd–O bond, depending on the identities of the reacting and ancillary ligands." @default.
- W2893803071 created "2018-10-05" @default.
- W2893803071 creator A5030200062 @default.
- W2893803071 creator A5043844658 @default.
- W2893803071 creator A5064798779 @default.
- W2893803071 creator A5088865204 @default.
- W2893803071 date "2018-09-25" @default.
- W2893803071 modified "2023-10-14" @default.
- W2893803071 title "Reductive Elimination to Form C(sp<sup>3</sup>)–N Bonds from Palladium(II) Primary Alkyl Complexes" @default.
- W2893803071 cites W1966608093 @default.
- W2893803071 cites W1969487950 @default.
- W2893803071 cites W1993436700 @default.
- W2893803071 cites W2000951812 @default.
- W2893803071 cites W2003667819 @default.
- W2893803071 cites W2027916341 @default.
- W2893803071 cites W2032795285 @default.
- W2893803071 cites W2041063003 @default.
- W2893803071 cites W2079581485 @default.
- W2893803071 cites W2094680700 @default.
- W2893803071 cites W2107918120 @default.
- W2893803071 cites W2126363023 @default.
- W2893803071 cites W2134629461 @default.
- W2893803071 cites W2138752984 @default.
- W2893803071 cites W2330552569 @default.
- W2893803071 cites W2341037910 @default.
- W2893803071 cites W2761811289 @default.
- W2893803071 cites W2792655947 @default.
- W2893803071 cites W4210969726 @default.
- W2893803071 doi "https://doi.org/10.1021/acs.organomet.8b00617" @default.
- W2893803071 hasPublicationYear "2018" @default.
- W2893803071 type Work @default.
- W2893803071 sameAs 2893803071 @default.
- W2893803071 citedByCount "10" @default.
- W2893803071 countsByYear W28938030712019 @default.
- W2893803071 countsByYear W28938030712020 @default.
- W2893803071 countsByYear W28938030712021 @default.
- W2893803071 countsByYear W28938030712023 @default.
- W2893803071 crossrefType "journal-article" @default.
- W2893803071 hasAuthorship W2893803071A5030200062 @default.
- W2893803071 hasAuthorship W2893803071A5043844658 @default.
- W2893803071 hasAuthorship W2893803071A5064798779 @default.
- W2893803071 hasAuthorship W2893803071A5088865204 @default.
- W2893803071 hasConcept C102931765 @default.
- W2893803071 hasConcept C116569031 @default.
- W2893803071 hasConcept C155647269 @default.
- W2893803071 hasConcept C161790260 @default.
- W2893803071 hasConcept C170493617 @default.
- W2893803071 hasConcept C178790620 @default.
- W2893803071 hasConcept C185592680 @default.
- W2893803071 hasConcept C197404232 @default.
- W2893803071 hasConcept C2778815869 @default.
- W2893803071 hasConcept C2780263894 @default.
- W2893803071 hasConcept C502130503 @default.
- W2893803071 hasConcept C55493867 @default.
- W2893803071 hasConcept C71240020 @default.
- W2893803071 hasConcept C94882840 @default.
- W2893803071 hasConceptScore W2893803071C102931765 @default.
- W2893803071 hasConceptScore W2893803071C116569031 @default.
- W2893803071 hasConceptScore W2893803071C155647269 @default.
- W2893803071 hasConceptScore W2893803071C161790260 @default.
- W2893803071 hasConceptScore W2893803071C170493617 @default.
- W2893803071 hasConceptScore W2893803071C178790620 @default.
- W2893803071 hasConceptScore W2893803071C185592680 @default.
- W2893803071 hasConceptScore W2893803071C197404232 @default.
- W2893803071 hasConceptScore W2893803071C2778815869 @default.
- W2893803071 hasConceptScore W2893803071C2780263894 @default.
- W2893803071 hasConceptScore W2893803071C502130503 @default.
- W2893803071 hasConceptScore W2893803071C55493867 @default.
- W2893803071 hasConceptScore W2893803071C71240020 @default.
- W2893803071 hasConceptScore W2893803071C94882840 @default.
- W2893803071 hasFunder F4320306076 @default.
- W2893803071 hasIssue "19" @default.
- W2893803071 hasLocation W28938030711 @default.
- W2893803071 hasOpenAccess W2893803071 @default.
- W2893803071 hasPrimaryLocation W28938030711 @default.
- W2893803071 hasRelatedWork W125841048 @default.
- W2893803071 hasRelatedWork W1984919548 @default.
- W2893803071 hasRelatedWork W1990342164 @default.
- W2893803071 hasRelatedWork W2020882448 @default.
- W2893803071 hasRelatedWork W2026695917 @default.
- W2893803071 hasRelatedWork W2052684020 @default.
- W2893803071 hasRelatedWork W2069314245 @default.
- W2893803071 hasRelatedWork W2435148650 @default.
- W2893803071 hasRelatedWork W2607290380 @default.
- W2893803071 hasRelatedWork W2949347669 @default.
- W2893803071 hasVolume "37" @default.
- W2893803071 isParatext "false" @default.
- W2893803071 isRetracted "false" @default.
- W2893803071 magId "2893803071" @default.
- W2893803071 workType "article" @default.