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- W2893823890 abstract "Palladium-catalyzed bond-forming reactions, such as the Suzuki–Miyaura and Mizoroki–Heck reactions, are some of the most broadly utilized reactions within the chemical industry. These reactions frequently employ hazardous solvents; however, to adhere to increasing sustainability pressures and restrictions regarding the use of such solvents, alternatives are highly sought after. Here we demonstrate the utility of dimethyl isosorbide (DMI) as a bio-derived solvent in several benchmark Pd-catalyzed reactions: Suzuki–Miyaura (13 examples, 62–100% yield), Mizoroki–Heck (13 examples, 47–91% yield), and Sonogashira (12 examples, 65–98% yield)." @default.
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- W2893823890 date "2018-09-28" @default.
- W2893823890 modified "2023-09-27" @default.
- W2893823890 title "Dimethylisosorbide (DMI) as a Bio-Derived Solvent for Pd-Catalyzed Cross-Coupling Reactions" @default.
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- W2893823890 doi "https://doi.org/10.1055/s-0037-1611054" @default.
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