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- W2893862390 abstract "PIDA/TBAB‐promoted oxidative geminal diazidofunctionalization of alkynes has been described for the first time. The transformation demonstrates a mechanistically distinctive approach to access geminal diazides, in which TBAB plays a crucial role as brominating agent and for the in situ generation of tetrabutylammonium azide. Furthermore, we have demonstrated here the first cycloaminative strategy by tactically employing the two azides groups leading to quinoxalines and synthesis of bis‐triazole derivatives via copper catalysis." @default.
- W2893862390 created "2018-10-05" @default.
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- W2893862390 date "2018-10-04" @default.
- W2893862390 modified "2023-10-06" @default.
- W2893862390 title "PIDA/TBAB-Promoted Oxidative Geminal Dibromofunctionalization of Alkynes: Direct Synthesis of Geminal Diazides" @default.
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- W2893862390 doi "https://doi.org/10.1002/ejoc.201801081" @default.
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