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- W2893869046 abstract "Abstract Degradation of alkali lignin (AL) is important for practical applications of this valuable natural resource. 12-Tungstophosphoric acid (TPA), supported on materials with a high surface area, has been shown to be an effective catalyst for the degradation of AL. This complex catalyst is, however, relatively unstable and there are a limited number of suitable supporting materials. To overcome these problems, we prepared ZrO2-supported TPA and demonstrated that this is an effective catalyst for the degradation of AL. Catalysts with different TPA loadings (10–40 wt%) were prepared using different calcinations temperatures (200–500 ℃). The catalysts were characterized by X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FESEM), and surface area measurements. Catalyst loaded with 20% TPA and prepared at 200 ℃ demonstrated the highest catalytic efficiency when the catalyst-to-lignin ratio was 1:8. Under these conditions, total hydroxyl groups and phenolic hydroxyl groups increased by 203.9% and 148.4%, respectively. The catalyst could be reused at least three times, without significant loss of activity. This method thus represents a green and effective alternative for the degradation of AL into valuable small molecules." @default.
- W2893869046 created "2018-10-05" @default.
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- W2893869046 date "2018-12-01" @default.
- W2893869046 modified "2023-10-14" @default.
- W2893869046 title "Zirconia-supported 12-tungstophosphoric acid: Characterization and catalytic behavior in degradation of alkali lignin" @default.
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- W2893869046 doi "https://doi.org/10.1016/j.indcrop.2018.09.035" @default.
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