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- W2893949876 abstract "This work deals with preparation, properties and reactivity of 1,2,3-diazaphospholederivatives. The first part summarizes data published in the literature; experimental partdescribes syntheses performed within the frame of this bachelor work. The new heterocycle4-ethyl-5-methyl-2H-1,2,3-diazaphosphole has been prepared and subsequently used for thesynthesis of bis(4-ethyl-5-methyl-1,2,3-diazaphosphol-2-yl)-dimethylsilane (L). Coordinationabilities of this compound toward selected transition metals have been studied. In twocomplexes of the formula [M(?Ű2-P,P-L)(CO)4] (M = Mo, W), the silane L behaves asphosphorus-bonded chelator, whereas in cobalt(II) compound [Co(?Ű2-N,N-L)Br2] is bondedto the central metal via two nitrogen donors." @default.
- W2893949876 created "2018-10-05" @default.
- W2893949876 creator A5043933226 @default.
- W2893949876 date "2018-01-01" @default.
- W2893949876 modified "2023-09-23" @default.
- W2893949876 title "Syntéza a reaktivita 4-ethyl-5-methyl-2H-[1,2,3]diazafosfolu" @default.
- W2893949876 hasPublicationYear "2018" @default.
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