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- W2894074736 abstract "The solvothermal reaction of Ti(OiPr)4, phosphorous acid and 2,2′-biphenol under different conditions offer three titanium-oxo clusters, namely, [Ti8(μ3-O)2(μ2-O)2(μ2-OiPr)4(OiPr)8(O3PH)4bph2], (bph = 2,2′-biphenolato) [Ti8(μ4-O)2(μ2-O)2(μ2-OEt)8(OEt)8(O3PH)2bph2], and [Ti4(μ3-O)2(μ2-OiPr)2(OiPr)4{O2P(OiPr)2}2bph2], respectively. The phosphite ligands induce the formation of different core structures compared to the well-studied phosphonate-stabilized titanium-oxo clusters. The 2,2′-biphenolato ligands introduce the ligand-to-core charge-transfer (LCCT) transition and result in narrow band gap of these clusters. Photocurrent response measurements show that the clusters with {Ti8P4} and {Ti8P2} core structures have higher photoelectrochemical activity than that of {Ti4P2}." @default.
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- W2894074736 date "2018-11-01" @default.
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- W2894074736 title "Syntheses, structures and photoelectrochemical properties of phosphite-stabilized titanium-oxo clusters containing 2,2′-biphenolato ligands" @default.
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- W2894074736 doi "https://doi.org/10.1016/j.inoche.2018.09.034" @default.
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