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• W2894097803 endingPage "12647" @default.
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• W2894097803 abstract "A direct iron(III)-catalyzed Prins–Peterson reaction involving α-substituted γ-triphenylsilyl bis-homoallylic alcohols and aldehydes is described. Thus, cis-Δ4-2,7-disubstituted oxepenes were synthesized in a diastereoselective reaction using sustainable catalytic conditions (3–5 mol %). This highly productive process is the result of a cascade of three chemical events with the concomitant formation of a C–O bond, a C–C bond, and a Δ4 endocyclic double bond, through a Prins cyclization followed by a Peterson-type elimination. This tandem reaction is chemoselective vs the classical Prins cyclization." @default.
• W2894097803 created "2018-10-05" @default.
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• W2894097803 date "2018-09-25" @default.
• W2894097803 modified "2023-10-13" @default.
• W2894097803 title "Iron-Catalyzed Prins–Peterson Reaction for the Direct Synthesis of Δ⁴-2,7-Disubstituted Oxepenes" @default.
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• W2894097803 doi "https://doi.org/10.1021/acs.joc.8b01978" @default.
• W2894097803 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30252471" @default.
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