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- W2894376945 startingPage "13843" @default.
- W2894376945 abstract "We report the use of LED-NMR spectroscopy to study the reaction mechanism of a newly discovered photoinduced iron-catalyzed cycloisomerization of alkynols to cyclic enol ethers. By understanding on/off ligand binding to the catalyst, we were able to appropriately design reaction conditions to balance catalyst activity and stability. LED-NMR was demonstrated to be a powerful tool in elucidating reaction mechanisms of photochemical reactions. Temporal NMR spectroscopic data under visible light illumination (1) revealed the pre-catalyst activation mechanism, (2) proved that photon flux provides a unique external control of the equilibrium distribution between the pre-catalyst and active catalyst, and ultimately the rate of reaction, (3) provided information about the reaction driving forces and the turnover-limiting step, and (4) enabled both real-time structural and kinetic insights into elusive species (e.g., dissolved gases)." @default.
- W2894376945 created "2018-10-05" @default.
- W2894376945 creator A5027960459 @default.
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- W2894376945 creator A5088374801 @default.
- W2894376945 date "2018-09-24" @default.
- W2894376945 modified "2023-09-27" @default.
- W2894376945 title "Discovery of a Photoinduced Dark Catalytic Cycle Using <i>in Situ</i> LED-NMR Spectroscopy" @default.
- W2894376945 cites W1897198241 @default.
- W2894376945 cites W1932762332 @default.
- W2894376945 cites W1964539326 @default.
- W2894376945 cites W1966865425 @default.
- W2894376945 cites W1968153979 @default.
- W2894376945 cites W1970171011 @default.
- W2894376945 cites W1971668582 @default.
- W2894376945 cites W1974199301 @default.
- W2894376945 cites W1979964905 @default.
- W2894376945 cites W1984642988 @default.
- W2894376945 cites W1985115408 @default.
- W2894376945 cites W1985636994 @default.
- W2894376945 cites W1986293903 @default.
- W2894376945 cites W1987411175 @default.
- W2894376945 cites W1989160593 @default.
- W2894376945 cites W1994881408 @default.
- W2894376945 cites W1998505449 @default.
- W2894376945 cites W1999635571 @default.
- W2894376945 cites W2011508390 @default.
- W2894376945 cites W2012432786 @default.
- W2894376945 cites W2014084443 @default.
- W2894376945 cites W2016456850 @default.
- W2894376945 cites W2018986006 @default.
- W2894376945 cites W2020563744 @default.
- W2894376945 cites W2022834076 @default.
- W2894376945 cites W2023064033 @default.
- W2894376945 cites W2028384952 @default.
- W2894376945 cites W2029019019 @default.
- W2894376945 cites W2035871617 @default.
- W2894376945 cites W2036059056 @default.
- W2894376945 cites W2042929771 @default.
- W2894376945 cites W2049249446 @default.
- W2894376945 cites W2051657460 @default.
- W2894376945 cites W2052089326 @default.
- W2894376945 cites W2060850694 @default.
- W2894376945 cites W2063360513 @default.
- W2894376945 cites W2064403926 @default.
- W2894376945 cites W2064881372 @default.
- W2894376945 cites W2065199219 @default.
- W2894376945 cites W2066567032 @default.
- W2894376945 cites W2076074161 @default.
- W2894376945 cites W2076336288 @default.
- W2894376945 cites W2078440574 @default.
- W2894376945 cites W2078965883 @default.
- W2894376945 cites W2079769968 @default.
- W2894376945 cites W2082110916 @default.
- W2894376945 cites W2082921139 @default.
- W2894376945 cites W2083900511 @default.
- W2894376945 cites W2085595472 @default.
- W2894376945 cites W2086165288 @default.
- W2894376945 cites W2086684498 @default.
- W2894376945 cites W2097445113 @default.
- W2894376945 cites W2097743599 @default.
- W2894376945 cites W2106900767 @default.
- W2894376945 cites W2108241347 @default.
- W2894376945 cites W2114991443 @default.
- W2894376945 cites W2121346396 @default.
- W2894376945 cites W2126349113 @default.
- W2894376945 cites W2129938616 @default.
- W2894376945 cites W2135571916 @default.
- W2894376945 cites W2140527049 @default.
- W2894376945 cites W2148065592 @default.
- W2894376945 cites W2157211386 @default.
- W2894376945 cites W2321899256 @default.
- W2894376945 cites W2322796022 @default.
- W2894376945 cites W2335422267 @default.
- W2894376945 cites W2342772717 @default.
- W2894376945 cites W2342892827 @default.
- W2894376945 cites W2406492823 @default.
- W2894376945 cites W2413230688 @default.
- W2894376945 cites W2443591564 @default.
- W2894376945 cites W2504256884 @default.
- W2894376945 cites W2514462360 @default.
- W2894376945 cites W2531137624 @default.
- W2894376945 cites W2551079503 @default.
- W2894376945 cites W2594855412 @default.
- W2894376945 cites W2611228636 @default.
- W2894376945 cites W2614282336 @default.
- W2894376945 cites W2732615433 @default.
- W2894376945 cites W2758580341 @default.
- W2894376945 cites W2761395933 @default.
- W2894376945 cites W2763232293 @default.
- W2894376945 cites W2769184618 @default.
- W2894376945 cites W2782017479 @default.
- W2894376945 cites W2782721227 @default.
- W2894376945 cites W2788910795 @default.