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W2894414864 abstract "The novel metalloid germanium cluster [Ge 9 (Hyp) 2 Hyp Ge ] – ( 1 ) was synthesized, exhibiting two different bulky groups [Hyp = Si(SiMe 3 ) 3 ; Hyp Ge = Ge(SiMe 3 ) 3 ]. Further reaction of 1 with ZnCl 2 gives the derivative [ZnGe 18 (Hyp) 4 (Hyp Ge ) 2 ] ( 2 ) in good yield, showing that the substitution of Si(SiMe 3 ) 3 by Ge(SiMe 3 ) 3 within a metalloid Ge 9 R 3 – compound leads to a comparable reactivity. 1 and 2 are characterized by NMR spectroscopy, mass spectrometry ( 1 ) and single crystal structure analyses ( 2 ). 1 and 2 are the first metalloid germanium clusters bearing germyl groups." @default.
W2894414864 created "2018-10-05" @default.
W2894414864 creator A5046152631 @default.
W2894414864 creator A5066626305 @default.
W2894414864 date "2018-09-24" @default.
W2894414864 modified "2023-10-18" @default.
W2894414864 title "[Ge9 {Si(SiMe3 )3 }2 {Ge(SiMe3 )3 }]- : The Mixed Substituted Metalloid Germanium Cluster and the Intermetalloid Cluster [ZnGe18 {Si(SiMe3 )3 }4 {Ge(SiMe3 )3 }2 ]" @default.
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W2894414864 doi "https://doi.org/10.1002/zaac.201800296" @default.
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