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- W2894419148 abstract "Abstract The bulky phenols 2,6-Ad 2 C 6 H 3 OH (Ad=adamantyl), A , (2,6-Ph 2 CH) 2 -4-Me-C 6 H 2 OH, B , and (2,6-Tol 2 CH) 2 -4- i Pr-C 6 H 2 OH, C , react with one equivalent of Et 3 M (M=Al, Ga), Bu 2 Mg and Et 2 Zn to afford well-defined mono-phenolate complexes (ArOMR n ) m . The aluminum and gallium phenolates derived from the very bulky phenol A are likely monomeric in the solid state. The other compounds are dimeric with bridging phenolates. Crystal structures of compounds with phenols B and C display the dimeric M 2 O 2 cores of the phenolates and illustrate some deviations for the magnesium and zinc compounds. The former possesses stabilizing Mg···C contacts with one of the flanking arene groups of the phenolate substituent, and the latter may be viewed as an intermediate between a symmetric dimer and two monomers. All compounds were characterized by 1 H and 13 C NMR spectroscopy, and their solution spectra are in agreement with the crystal structure data." @default.
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- W2894419148 date "2018-09-24" @default.
- W2894419148 modified "2023-10-17" @default.
- W2894419148 title "Alkylaluminum, -gallium, -magnesium, and -zinc monophenolates with bulky substituents" @default.
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- W2894419148 doi "https://doi.org/10.1515/znb-2018-0176" @default.
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