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- W2894425292 abstract "5-exo, 5-exo Cyclizations of conformationally unbiased propargylic aminyl radicals proceed with excellent yield, chemoselectivity, and diastereoselectivity under tin-free reductive cyclization conditions, regardless of the electronic environments and intermediate radical stabilization resulting from various olefin substituents. These conditions avoid the need for slow addition of initiator and reductant. By contrast, analogous 6-exo, 5-exo cyclizations require substituents capable of intermediate radical stabilization to avoid premature reduction products. These experimental results are corroborated by computations that further establish the reactivity of these aminyl radicals upon exposure to tin-free cyclization conditions." @default.
- W2894425292 created "2018-10-05" @default.
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- W2894425292 date "2018-09-28" @default.
- W2894425292 modified "2023-10-09" @default.
- W2894425292 title "Synthetic and Computational Study of Tin-Free Reductive Tandem Cyclizations of Neutral Aminyl Radicals" @default.
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- W2894425292 doi "https://doi.org/10.1021/acs.orglett.8b02456" @default.
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