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- W2894486540 abstract "The reaction of tetraphenylcyclopentadienone with Co2(CO)8 generates the mixed-valence tricobalt complex [Ph4C4CO]Co(CO)2]2[μ-Co(MeCN)2]. In contrast to the conventional Pauson–Khand reaction to generate cyclopentadienone-ligated cobalt complexes, this method benefits from both mild reaction conditions and high yields. Treatment of this tricobalt complex with proton sources such as water or alcohols yields the monomeric hydroxytetraphenylcyclopentadienyl cobalt complex [Ph4CpOH]Co(CO)2. Phosphite substituted monomeric cobalt complexes [Ph4CpOH]Co(CO)[P(OR)3] were also synthesized, and protonation of these complexes transiently formed cobalt hydride species." @default.
- W2894486540 created "2018-10-05" @default.
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- W2894486540 date "2018-09-24" @default.
- W2894486540 modified "2023-10-18" @default.
- W2894486540 title "Synthesis, Characterization, and Reactivity of Hydroxycyclopentadienyl Cobalt Complexes" @default.
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- W2894486540 doi "https://doi.org/10.1021/acs.organomet.8b00486" @default.
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