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- W2894490758 abstract "Mixed-phase TiO2 nanoparticles (10–20 nm) composed of rutile, anatase, and srilankite phases are prepared through a one-step flame synthesis method. The phase composition of TiO2 nanoparticles can be easily tuned by changing the flame conditions such as the gas flow rates of the fuel, oxygen, and argon carrier. The optimized anatase/rutile/srilankite TiO2 sample with as low as 0.1 wt % of Pt cocatalyst exhibits remarkable photocatalytic H2 generation rate of 21.9 mmol h–1 g–1 and an apparent quantum efficiency (AQE) of 39.4% at 360 nm, higher than those of anatase/rutile or anatase TiO2. The less studied srilankite phase is first time investigated for photocatalytic H2 generation. It is revealed that the relatively low content of srilankite phase in TiO2 could efficiently promote charge separation and transportation. It is remarkable that, compared to the commercial P25 TiO2, the flame-made TiO2 significantly improves Pt reduction and dispersion owing to the oxygen vacancies and surface defects. The optim..." @default.
- W2894490758 created "2018-10-05" @default.
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- W2894490758 date "2018-09-25" @default.
- W2894490758 modified "2023-10-14" @default.
- W2894490758 title "Premixed Stagnation Flame Synthesized TiO<sub>2</sub> Nanoparticles with Mixed Phases for Efficient Photocatalytic Hydrogen Generation" @default.
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- W2894490758 doi "https://doi.org/10.1021/acssuschemeng.8b03142" @default.
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