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- W2894494480 abstract "A carbene-catalyzed enantioselective addition of benzylic carbon to α,β-unsaturated acyl azolium intermediate generated via N-heterocyclic carbene catalysis is disclosed. This addition is followed by a stereoselective Mannich reaction and a chemo-selective lactam formation cascade to afford pyrrolo[3,2-c]quinolones as the products with excellent yields and optical purities. This work constitutes an effective asymmetric benzyl sp3-carbon functionalization and single-step rapid access to multicyclic heterocycles bearing four contiguous chiral centers." @default.
- W2894494480 created "2018-10-05" @default.
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- W2894494480 date "2018-09-25" @default.
- W2894494480 modified "2023-10-14" @default.
- W2894494480 title "Carbene-Catalyzed Enantioselective Addition of Benzylic Carbon to Unsaturated Acyl Azolium for Rapid Synthesis of Pyrrolo[3,2-<i>c</i>]quinolines" @default.
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- W2894494480 doi "https://doi.org/10.1021/acscatal.8b02651" @default.
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