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- W2894510063 abstract "There are millions of tonnes of petroleum coke stockpiled worldwide, but to take advantage of this potential resource, a better understanding of how to activate this feedstock with less waste is required. The impact of steam addition during chemical activation of petroleum coke with a high sulfur content (~6.5 wt%) was evaluated with two chemical agents (KOH and NaOH), chemical molar ratios (from 0.12 to 1.02 or mass ratios from 0.5 to 3) and activation times (0 to 120 min) at 1073 K. Based on the yield and total pore volume developed, co-activation of KOH and steam was an effective way to reduce the amount of chemical agent required, while widening the pores from ~ 1 nm to up to 4 nm. In contrast, the addition of steam to the activation with NaOH resulted in less pore development and essentially no change in the pore size. At the activation conditions, there is likely a molten phase around the particles that slows steam gasification and has a composition that changes with the introduction of steam." @default.
- W2894510063 created "2018-10-05" @default.
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- W2894510063 date "2018-12-01" @default.
- W2894510063 modified "2023-10-06" @default.
- W2894510063 title "Impacts of amount of chemical agent and addition of steam for activation of petroleum coke with KOH or NaOH" @default.
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- W2894510063 doi "https://doi.org/10.1016/j.fuproc.2018.09.018" @default.
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