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- W2894557875 endingPage "12755" @default.
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- W2894557875 abstract "Three pentacoordinate complexes of the type [Co(pypz)X2], where pypz is a tridentate ligand 2,6-bis(pyrazol-1-yl)pyridine and X = Cl– (1), NCS– (2), and NCO– (3), have been synthesized, and their structures have been determined by X-ray analysis. The DC magnetic data show a sizable magnetic anisotropy, which was confirmed by high-field high-frequency electron paramagnetic resonance (HF EPR) measurements. Well-resolved HF EPR spectra of high spin cobalt (II) were observed over the microwave frequency range 100–650 GHz. The experimental spectra of both complexes were simulated with axial g tensor components, a very large positive D value, and different E/D ratios. To determine the exact D value for 2 (38.4 cm–1) and 3 (40.92 cm–1), the far-infrared magnetic spectroscopy method was used. Knowledge of the zero field splitting parameters and their signs is crucial in interpreting the single-molecule magnet or single chain magnet behavior. The AC susceptibility data confirm that these complexes exhibit a slow magnetic relaxation under small applied DC field with two (1 and 3) or three (2) relaxation modes." @default.
- W2894557875 created "2018-10-12" @default.
- W2894557875 creator A5011381513 @default.
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- W2894557875 date "2018-10-02" @default.
- W2894557875 modified "2023-10-17" @default.
- W2894557875 title "Slow Magnetic Relaxation in Cobalt(II) Field-Induced Single-Ion Magnets with Positive Large Anisotropy" @default.
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