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- W2894577076 abstract "Biomethane is a sustainable biofuel composed of methane and minor components such as CO2, O2 or H2S. The presence of O2 can be deleterious for the integrity of the pipelines and gas storage systems, as it causes corrosion and may involve explosions. Therefore, O2 monitoring in biomethane has become mandatory. European Standard EN16723 establishes maximum limits allowed for its injection into the natural gas distribution grid or its use as a vehicle fuel. Consequently, reliable O2 monitors must be installed in biomethane production plants. We have developed sensitive, selective, sturdy luminescent optosensors for in situ real-time O2 measurements in biomethane using selected Ru (II) polypyridyls and supports. The sensing layers are interrogated with a dedicated field-deployable fiberoptic phase-sensitive luminometer. The detailed manufacturing, analytical characterization and testing of the O2 optosensors are reported herein. They display a ca. 1–10000 ppmv O2 range, response (t90) and recovery times (t-90) shorter than 30 s, and repeatability and reproducibility better than 6.5%, all without interference from other components (CH4, CO2, NH3, H2S or mercaptans). The performance of one prototype has been verified for more than 1 year for discontinuous measurements and more than 6 months at a biomethane production plant in southern Spain." @default.
- W2894577076 created "2018-10-12" @default.
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- W2894577076 date "2019-01-01" @default.
- W2894577076 modified "2023-10-04" @default.
- W2894577076 title "Luminescent sensor for O2 detection in biomethane streams" @default.
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- W2894577076 doi "https://doi.org/10.1016/j.snb.2018.09.108" @default.
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